364010
(1R,2R)-(+)-1,2-Diphenylethylenediamine
97%
Synonym(s):
(1R,2R)- DPEDA, (1R,2R)-DPEN, (1R,2R)-(+)-1,2-Diamino-1,2-diphenylethane
About This Item
Recommended Products
Quality Level
Assay
97%
optical activity
[α]20/D +102°, c = 1 in ethanol
optical purity
ee: 99% (GLC)
mp
79-83 °C (lit.)
functional group
amine
phenyl
SMILES string
N[C@@H]([C@H](N)c1ccccc1)c2ccccc2
InChI
1S/C14H16N2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-14H,15-16H2/t13-,14-/m1/s1
InChI key
PONXTPCRRASWKW-ZIAGYGMSSA-N
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Application
- (1R,2R)-(+)-1,2-Diphenylethylenediamine (DPEN) is one of the widely used chiral auxiliary and ligand in the synthesis of asymmetric catalysts such as BINAP/diamine-Ru complexes for the stereoselective hydrogenation of ketones.
- It can be used in the preparation of monosulfonyl DPEN-salt to catalyze Michael addition of various ketones to maleimides.
- DPEN-derived chiral triazolium salts can be used to catalyze enantioselective intramolecular Stetter reaction and oxodiene Diels-Alder reaction.
- Zinc acetate complexes of DPEDA-derived ligands can also be used to catalyze hydrosilylation of imines.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
JAN Code
364010-100MG:
364010-BULK:
364010-1G:
364010-500MG:
364010-VAR:
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