703907
RuCl(p-cymene)[(R,R)-Ts-DPEN]
Synonym(s):
[N-[(1R,2R)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-ruthenium
About This Item
Recommended Products
form
powder
Quality Level
optical activity
[α]20/D −116°, c = 0.1 in chloroform
mp
215 °C
functional group
amine
phenyl
storage temp.
2-8°C
SMILES string
CC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4
InChI
1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1
InChI key
AZFNGPAYDKGCRB-AGEKDOICSA-M
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General description
Application
- Quinolines
- N-Alkyl ketimines
- Antitumor and antiproliferative derivatives of natural products isolated from bacteria
- Hydroxy arylaldehydes via Rap-Stoermer-enantioselective transfer hydrogenation
Catalyst with improved performance modified via microenvironment engineering of nanocages
Legal Information
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
JAN Code
703907-VAR:
703907-500MG:
703907-BULK:
703907-100MG:
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Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago
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