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341568

Sigma-Aldrich

Benzeneruthenium(II) chloride dimer

Synonym(s):

(Benzene)dichlororuthenium dimer, Benzeneruthenium dichloride dimer, Bis(benzene)tetrachlorodiruthenium, Bis[(benzene)dichlororuthenium], Dibenzenetetrachlorodiruthenium

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About This Item

Linear Formula:
Ru2(C6H6)2Cl4
CAS Number:
37366-09-9
Molecular Weight:
500.18
MDL number:
MFCD00064686
UNSPSC Code:
12161600
PubChem Substance ID:
24860964
NACRES:
NA.22

reaction suitability

core: ruthenium
reagent type: catalyst

SMILES string

Cl[Ru]Cl.Cl[Ru]Cl.c1ccccc1.c2ccccc2

InChI

1S/2C6H6.4ClH.2Ru/c2*1-2-4-6-5-3-1;;;;;;/h2*1-6H;4*1H;;/q;;;;;;2*+2/p-4

InChI key

YGXMUPKIEHNBNQ-UHFFFAOYSA-J

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Related Categories

Application

Hydrosilylation Catalysts

  • Catalyst for SNAr reactions of fluoroarenes and cyclic amines (eq. 1)
  • Precatalyst for the hydrogenation of β-keto esters (eq. 2)
  • Precursor for the preparation of other ruthenium catalysts (eq. 3)

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

341568-5G:
341568-BULK:
341568-VAR:
341568-1G:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCL7737
MKBX7632V
MKBM6612V
38497PJV
38497PJ

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Articles

Hydrosilylation Catalyst

A Highly Efficient Hydrosilylation Catalyst, sigma-aldrich is pleased to offer [Cp*Ru(MeCN)3]PF6, as well as a number of other catalysts for hydrosilylation.

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