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Safety Information

646075

Sigma-Aldrich

p-Tolylmagnesium bromide solution

0.5 M in diethyl ether

Synonym(s):

4-Methylphenylmagnesium bromide

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About This Item

Linear Formula:
CH3C6H4MgBr
CAS Number:
4294-57-9
Molecular Weight:
195.34
Beilstein:
636491
MDL number:
MFCD00000040
UNSPSC Code:
12352103
PubChem Substance ID:
24883432
NACRES:
NA.22

Quality Level

100

reaction suitability

reaction type: Grignard Reaction

concentration

0.5 M in diethyl ether

SMILES string

Cc1ccc([Mg]Br)cc1

InChI

1S/C7H7.BrH.Mg/c1-7-5-3-2-4-6-7;;/h3-6H,1H3;1H;/q;;+1/p-1

InChI key

ZRJNGFJIBZKXTP-UHFFFAOYSA-M

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Signal Word

Danger

Hazard Statements

H224,H302,H314,H336

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system

Supplementary Hazards

EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

-40.0 °F - closed cup - Solvent

Flash Point(C)

-40 °C - closed cup - Solvent

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 3: Spontaneously combustible substances and water- reactive materials
Materials containing Organometallic compounds
Hazardous rank I
1st spontaneously combustible materials and water reactive materials

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

646075-100ML:4548173176154
646075-800ML:4548173176161
646075-VAR:
646075-BULK:

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Certificates of Analysis (COA)

Lot/Batch Number
SHBM8671
SHBM6269
SHBF4418V
04796LK
08103KE179

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Ekaterina A Dolgopolova et al.
Journal of the American Chemical Society, 141(13), 5350-5358 (2019-03-07)
Electronic structure modulation of metal-organic frameworks (MOFs) through the connection of linker "wires" as a function of an external stimulus is reported for the first time. The established correlation between MOF electronic properties and photoisomerization kinetics as well as changes
Derek E Williams et al.
Journal of the American Chemical Society, 140(24), 7611-7622 (2018-05-29)
Stimuli-responsive materials are vital for addressing emerging demands in the advanced technology sector as well as current industrial challenges. Here, we report for the first time that coordinative integration of photoresponsive building blocks possessing photochromic spiropyran and diarylethene moieties within

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