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687901

Sigma-Aldrich

4-(Trifluoromethoxy)phenylmagnesium bromide solution

0.5 M in THF

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About This Item

Empirical Formula (Hill Notation):
C7H4BrF3MgO
Molecular Weight:
265.31
MDL number:
MFCD09842767
UNSPSC Code:
12352103
PubChem Substance ID:
329760826
NACRES:
NA.22

form

liquid

reaction suitability

reaction type: Grignard Reaction

concentration

0.5 M in THF

density

0.975 g/mL at 25 °C

functional group

fluoro

SMILES string

FC(F)(F)Oc1ccc([Mg]Br)cc1

InChI

1S/C7H4F3O.BrH.Mg/c8-7(9,10)11-6-4-2-1-3-5-6;;/h2-5H;1H;/q;;+1/p-1

InChI key

UFMHNMPAQCQXMW-UHFFFAOYSA-M

Related Categories

Application

Reactant for:
  • Preparation of chromanol derivatives as novel class of CETP inhibitors for treatment of cardiovascular disease
  • Pd-catalyzed cross coupling
  • Preparation of indazole-pyridine derivatives as protein kinase B/Akt inhibitors with reduced hypotension, via Stille coupling, Mitsunobu reaction and copper-catalyzed aziridine ring-opening reaction

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH014,EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

-22.0 - -4.0 °F - closed cup

Flash Point(C)

-30 - -20 °C - closed cup

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 3: Spontaneously combustible substances and water- reactive materials
Materials containing Organometallic compounds
Hazardous rank I
1st spontaneously combustible materials and water reactive materials

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

687901-50ML:4548173290645
687901-BULK:
687901-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
SHBG6030V
SHBD6010V
SHBC6055
40996DM
37196PK

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