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Safety Information

360023

Sigma-Aldrich

o-Tolylmagnesium chloride solution

1.0 M in THF

Synonym(s):

2-Methylphenylmagnesium chloride

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About This Item

Linear Formula:
CH3C6H4MgCl
CAS Number:
33872-80-9
Molecular Weight:
150.89
Beilstein:
3537703
MDL number:
MFCD00010355
UNSPSC Code:
12352103
PubChem Substance ID:
24862138
NACRES:
NA.22

reaction suitability

reaction type: Grignard Reaction

concentration

1.0 M in THF

density

0.956 g/mL at 25 °C

SMILES string

Cc1ccccc1[Mg]Cl

InChI

1S/C7H7.ClH.Mg/c1-7-5-3-2-4-6-7;;/h2-5H,1H3;1H;/q;;+1/p-1

InChI key

DSJSQDNPAOUFOJ-UHFFFAOYSA-M

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Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH014,EUH019

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

3.2 °F - closed cup

Flash Point(C)

-16 °C - closed cup

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 3: Spontaneously combustible substances and water- reactive materials
Materials containing Organometallic compounds
Hazardous rank I
1st spontaneously combustible materials and water reactive materials

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

360023-VAR:
360023-BULK:
360023-800ML:4548173139265
360023-100ML:4548173139258

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Certificates of Analysis (COA)

Lot/Batch Number
SHBK5418
SHBK0311
SHBG2372V
SHBC4860V
S47717

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Oleg V Larionov et al.
Organic letters, 16(3), 864-867 (2014-01-15)
A one-step transformation of heterocyclic N-oxides to 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles is described. The success of this broad-scope methodology hinges on the combination of copper catalysis and activation by lithium fluoride or magnesium chloride. The utility of this method

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