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Key Documents

Safety Information

359386

Sigma-Aldrich

Manganese(II) perchlorate hydrate

99%

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About This Item

Linear Formula:
Mn(ClO4)2·xH2O
CAS Number:
Molecular Weight:
253.84 (anhydrous basis)
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Assay

99%

form

crystalline

reaction suitability

reagent type: oxidant

application(s)

battery manufacturing

SMILES string

O.[Mn++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O

InChI

1S/2ClHO4.Mn.H2O/c2*2-1(3,4)5;;/h2*(H,2,3,4,5);;1H2/q;;+2;/p-2

InChI key

VAZHKDVMMUBWIG-UHFFFAOYSA-L

Application

Starting material for homometallic, trinuclear heteroscorpionate complexes applied in studies of electronic and magnetic properties.

Pictograms

Flame over circleExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 1: Oxidizing solids
Perchlorates
Hazardous rank I
1st oxidizing solid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

359386-100G:4548173938646
359386-500G:
359386-BULK:
359386-VAR:


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Timothy C. Higgs et al.
Inorganic chemistry, 37(9), 2263-2272 (2001-10-24)
The mixed functionality pyrazole/phenol ligand (2-hydroxyphenyl)bis(pyrazolyl)methane, L1OH, has been used to prepare a series of linear trimetallic systems with the general structural motif [M(3)(L1O)(4)](2+), where M = Mn(2+), Co(2+), Ni(2+), Cu(2+), and Zn(2+). Each of these complexes has been structurally

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