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715301

Sigma-Aldrich

Manganese bis(trifluoromethanesulfonate)

Synonym(s):

Manganese triflate, Manganese trifluoromethanesulfonate

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About This Item

Empirical Formula (Hill Notation):
C2F6MnO6S2
CAS Number:
55120-76-8
Molecular Weight:
353.08
MDL number:
MFCD17015267
UNSPSC Code:
12161600
PubChem Substance ID:
329762961
NACRES:
NA.22

form

solid

Quality Level

100

reaction suitability

core: manganese
reagent type: catalyst

impurities

5% metallic Mn

mp

>400 °C

SMILES string

FC(F)(F)S(=O)(=O)O[Mn]OS(=O)(=O)C(F)(F)F

InChI

1S/2CHF3O3S.Mn/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2

InChI key

HEYNLDRKZOOEDN-UHFFFAOYSA-L

General description

Manganese bis(trifluoromethanesulfonate) is also known as manganese triflate. It is used as a catalyst in organic synthesis for the oxidation of various hydrocarbons, epoxidation, and C-H oxidation reactions.

Application

Catalyst for:
  • Biginelli reactions
  • Methanolysis

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302,H314

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

715301-1G:4548173924205
715301-VAR:
715301-BULK:

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Certificates of Analysis (COA)

Lot/Batch Number
SHBN6677
SHBN0596
SHBK2843
SHBH7836
SHBF9379V

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