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309338

Sigma-Aldrich

Nickel(II) perchlorate hexahydrate

Synonym(s):

Nickel(2+) diperchlorate hexahydrate

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About This Item

Linear Formula:
Ni(ClO4)2 · 6H2O
CAS Number:
13520-61-1
Molecular Weight:
365.69
EC Number:
237-124-1
MDL number:
MFCD00149804
UNSPSC Code:
12352302
PubChem Substance ID:
24858728
NACRES:
NA.23
form:
crystalline

form

crystalline

Quality Level

100

reaction suitability

reagent type: oxidant

concentration

15.3-17.0% Ni (EDTA titration)

mp

140 °C (lit.)

application(s)

battery manufacturing

SMILES string

O.O.O.O.O.O.[Ni++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O

InChI

1S/2ClHO4.Ni.6H2O/c2*2-1(3,4)5;;;;;;;/h2*(H,2,3,4,5);;6*1H2/q;;+2;;;;;;/p-2

InChI key

WHGYCGOFTBFDLW-UHFFFAOYSA-L

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Application

Starting material for homometallic, trinuclear heteroscorpionate complexes applied in studies of electronic and magnetic properties.

Signal Word

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Eye Dam. 1 - Muta. 2 - Ox. Sol. 3 - Repr. 1B - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 1

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Specified Class I Designated Chemical Substances

FSL

Group 1: Oxidizing solids
Perchlorates
Hazardous rank I
1st oxidizing solid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

309338-VAR:
309338-500G:4548173294117
309338-100G:4548173294100
309338-5G:4548173294124
309338-BULK:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ4591
MKCN5211
MKCK4254
MKCG4736
MKCC2032

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Timothy C. Higgs et al.
Inorganic chemistry, 37(9), 2263-2272 (2001-10-24)
The mixed functionality pyrazole/phenol ligand (2-hydroxyphenyl)bis(pyrazolyl)methane, L1OH, has been used to prepare a series of linear trimetallic systems with the general structural motif [M(3)(L1O)(4)](2+), where M = Mn(2+), Co(2+), Ni(2+), Cu(2+), and Zn(2+). Each of these complexes has been structurally

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