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326348

Sigma-Aldrich

Iron(III) perchlorate hydrate

crystalline, low chloride

Synonym(s):

Perchloric acid iron(III) salt hydrate

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About This Item

Linear Formula:
Fe(ClO4)3 · xH2O
CAS Number:
15201-61-3
Molecular Weight:
354.20 (anhydrous basis)
EC Number:
236-908-0
MDL number:
MFCD00149705
UNSPSC Code:
12352000
PubChem Substance ID:
24859580
NACRES:
NA.22

Quality Level

200

form

crystalline

reaction suitability

reagent type: oxidant

impurities

<0.005% chloride

color

pale violet

SMILES string

[Fe+3].[H]O[H].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O

InChI

1S/3ClHO4.Fe.H2O/c3*2-1(3,4)5;;/h3*(H,2,3,4,5);;1H2/q;;;+3;/p-3

InChI key

PFPIMAZLJXJVAN-UHFFFAOYSA-K

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Application

Catalyst for synthesis of:
  • Fullerene-fused lactones
  • α-Carbonyl furans via one-pot cyclization
  • Fullerodioxolanes via heterocyclization
  • Dialylated indoles via double alkylation
  • Aryl esters via oxidative esterification

Used as chemical actinometer based on photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution

Oxidant for conducting polymer nanoparticles synthesized in ionic liquid by chemical polymerization
Useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units which allow two coordination modes.

Pictograms

Flame over circleExclamation mark
GHS03,GHS07

Signal Word

Danger

Hazard Statements

H272,H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 1: Oxidizing solids
Perchlorates
Hazardous rank I
1st oxidizing solid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

326348-500G:4548173937359
326348-100G:4548173937342
326348-BULK:
326348-VAR:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Structural Characterization of a Tris-salicylate Coordination for Iron(III) with the Tripodal Ligand O-TRENSOX.
Guy Serratrice et al.
Inorganic chemistry, 38(5), 840-841 (2001-10-24)

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