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Safety Information

254150

Sigma-Aldrich

Bismuth(III) nitrate pentahydrate

99.999% trace metals basis

Synonym(s):

Bismuth trinitrate pentahydrate

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About This Item

Linear Formula:
Bi(NO3)3 · 5H2O
CAS Number:
10035-06-0
Molecular Weight:
485.07
EC Number:
233-791-8
UNSPSC Code:
12352302
PubChem Substance ID:
24855361
NACRES:
NA.22

Quality Level

100

Assay

99.999% trace metals basis

form

crystals

reaction suitability

core: bismuth
reagent type: catalyst

bp

75-80 °C (lit.)

mp

30 °C (lit.)

SMILES string

O=[N+](O[Bi](O[N+]([O-])=O)O[N+]([O-])=O)[O-].C

InChI

1S/CH4.Bi.3NO3/c;;3*2-1(3)4/h1H4;;;;/q;+3;3*-1

InChI key

DPLOIMSBRDLLRI-UHFFFAOYSA-N

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Application

An excellent oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines. Convenient reagent for selective oxidation of sufides to sulfoxides.

Pictograms

Flame over circleCorrosion
GHS03,GHS05

Signal Word

Danger

Hazard Statements

H272,H318

Hazard Classifications

Eye Dam. 1 - Ox. Sol. 2

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 1: Oxidizing solids
Nitrates
Hazardous rank III
3rd oxidizing solid

JAN Code

254150-100G:
254150-BULK:
254150-5G:
254150-VAR:
254150-25G:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ2974
MKCN4567
MKCM0651
MKCH3051
MKCF2958

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Guojun Han et al.
Cytometry. Part A : the journal of the International Society for Analytical Cytology, 91(12), 1150-1163 (2017-12-06)
Mass cytometry (or CyTOF) is an atomic mass spectrometry-based single-cell immunoassay technology, which has provided an increasingly systematic and sophisticated view in basic biological and clinical studies. Using elemental reporters composed of stable heavy metal isotopes, more than 50 cellular
Mashraqui, S.H. Karnik, M.A.
Synthesis, 713-713 (1998)
Mashraqui, S.H. et al.
Synthetic Communications, 28, 939-939 (1998)
Na Li et al.
Dalton transactions (Cambridge, England : 2003), 43(36), 13742-13750 (2014-08-12)
The xFe2O3/yBiOCl composites (xFe/yBi, x/y = 0/100, 5/100, 10/100, 20/100, 30/100 and 40/100 molar ratios) are prepared for the first time through an in situ hydrolysis method under hydrothermal conditions. The samples are characterized by X-ray diffraction (XRD), scanning electron
Nahid Gharib Naseri et al.
Analytical and bioanalytical chemistry, 391(4), 1283-1292 (2008-03-21)
Catalytic adsorptive stripping voltammetry (CAdSV) has been demonstrated at a bismuth film electrode (BiFE) in an injection-moulded electrochemical micro-flow cell. The polystyrene three-electrode flow cell was fabricated with electrodes moulded from a conducting grade of polystyrene containing 40% carbon fibre
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