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205699

Sigma-Aldrich

Palladium on carbon

greener alternative

extent of labeling: 10 wt. % loading, matrix activated carbon support

Synonym(s):

Pd/C

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About This Item

Linear Formula:
Pd
Molecular Weight:
106.42
MDL number:
MFCD03457879
UNSPSC Code:
12141733
eCl@ss:
38191001
PubChem Substance ID:
24852339
NACRES:
NA.22

form

powder

Quality Level

200

reaction suitability

core: palladium
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Buchwald-Hartwig Cross Coupling Reaction

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

extent of labeling

10 wt. % loading

matrix

activated carbon support

greener alternative category

Enabling,

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Catalyst for:
  • Stille reaction
  • Hydrogenation reactions
  • Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions
  • Deoxygenation
  • Oxidation reactions
  • Coupling reactions
Palladium on carbon (Pd/C) (10 wt. % loading, matrix activated carbon support) can be used as a catalyst in the well known reactions like hydrogenation of alkenes, alkynes, ketones, nitriles, imines, azides, nitro groups, benzenoid and heterocyclic aromatics; hydrogenolysis of cyclopropanes, benzyl derivatives, epoxides, hydrazines, and halides; dehydrogenate aromatics and deformylate aldehydes.
It can also be used as:

  • A catalyst for hydrodechlorination of dichlorodifluoromethane (CCl2F2), which is a known greenhouse gas,
  • A catalyst for Heck reactions of aryl halides in ionic liquids
  • An anode catalyst for the fabrication of direct formic acid fuel cells (DFAFC)
  • A cost-effective electrocatalyst for the oxidation of methanol
  • In the catalytic hydrogenation of chemical hydrides for the production of hydrogen
  • A catalyst in Suzuki-Mayaura reaction
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

205699-BULK:
205699-250G:
205699-VAR:
205699-10G:
205699-50G:
205699-5KG:
205699-1G:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ4022
MKCQ3466
MKCQ1545
MKCP8594
MKCP6852

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Pd/C: an old catalyst for new applications-its use for the Suzuki-Miyaura reaction
Felpin F, et al.
European Journal of Organic Chemistry, 2006(12), 2679-2690 (2006)
Pd-C powder and thin film catalysts for hydrogen production by hydrolysis of sodium borohydride
Patel N, et al.
International Journal of Hydrogen Energy, 33(1), 287-292 (2008)
Heterogeneous Heck reaction catalyzed by Pd/C in ionic liquid
Hagiwara H, et al.
Tetrahedron Letters, 42(26), 4349-4351 (2001)
Characterisation of the deactivation of platinum and palladium supported on activated carbon used as hydrodechlorination catalysts
Ordonez S, et al.
Applied Catalysis. B, Environmental, 31(2), 113-122 (2001)
Konstantina C Fylaktakidou et al.
ChemMedChem, 6(1), 153-168 (2010-11-26)
Polyphosphorylated and perphosphorylated hexopyranose monosaccharides and disaccharides were synthesized from parent or partially protected carbohydrates as potential allosteric effectors of hemoglobin. A study toward the construction of seven- and eight-membered cyclic pyrophosphates was also performed on the sugars which had

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