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467839

Sigma-Aldrich

Bismuth(III) nitrate pentahydrate

≥99.99% trace metals basis

Synonym(s):

Bismuth trinitrate pentahydrate

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About This Item

Linear Formula:
Bi(NO3)3 · 5H2O
CAS Number:
10035-06-0
Molecular Weight:
485.07
EC Number:
233-791-8
UNSPSC Code:
12161600
PubChem Substance ID:
24870440
NACRES:
NA.22

Assay

≥99.99% trace metals basis

form

solid

reaction suitability

core: bismuth
reagent type: catalyst

impurities

≤0.005% insolubles
<100 ppm total metallic impurities

bp

75-80 °C (lit.)

mp

30 °C (lit.)

anion traces

chloride (Cl-): ≤0.001%
sulfate (SO42-): ≤0.005%

cation traces

Ag: ≤0.001%
As: ≤0.001%
Ca: ≤0.005%
Cu: ≤0.002%
Fe: ≤0.001%
K: ≤0.01%
Na: ≤0.02%
Pb: ≤0.002%

SMILES string

O=[N+](O[Bi](O[N+]([O-])=O)O[N+]([O-])=O)[O-].C

InChI

1S/CH4.Bi.3NO3/c;;3*2-1(3)4/h1H4;;;;/q;+3;3*-1

InChI key

DPLOIMSBRDLLRI-UHFFFAOYSA-N

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Application

An excellent oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines. Convenient reagent for selective oxidation of sufides to sulfoxides.

Pictograms

Flame over circleCorrosion
GHS03,GHS05

Signal Word

Danger

Hazard Statements

H272,H318

Hazard Classifications

Eye Dam. 1 - Ox. Sol. 2

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 1: Oxidizing solids
Nitrates
Hazardous rank III
3rd oxidizing solid

JAN Code

467839-250G:
467839-VAR:
467839-BULK:
467839-50G:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Xiao-Dong Zhang et al.
Nanomedicine : nanotechnology, biology, and medicine, 13(5), 1597-1605 (2017-03-13)
Bi
Yukti Arora et al.
Scientific reports, 8(1), 12752-12752 (2018-08-26)
Storage of solar radiation is currently accomplished by coupling two separate devices, one that captures and converts the energy into an electrical impulse (a photovoltaic cell) and another that stores this electrical output (a battery or a supercapacitor electrochemical cell).
Mashraqui, S.H. Karnik, M.A.
Synthesis, 713-713 (1998)
Mashraqui, S.H. et al.
Synthetic Communications, 28, 939-939 (1998)
Na Li et al.
Dalton transactions (Cambridge, England : 2003), 43(36), 13742-13750 (2014-08-12)
The xFe2O3/yBiOCl composites (xFe/yBi, x/y = 0/100, 5/100, 10/100, 20/100, 30/100 and 40/100 molar ratios) are prepared for the first time through an in situ hydrolysis method under hydrothermal conditions. The samples are characterized by X-ray diffraction (XRD), scanning electron
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