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Safety Information

206075

Sigma-Aldrich

Potassium tetrachloroplatinate(II)

98%

Synonym(s):

Potassium platinum(II) chloride

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About This Item

Linear Formula:
K2PtCl4
CAS Number:
Molecular Weight:
415.09
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

98%

form

solid

density

3.38 g/mL at 25 °C (lit.)

SMILES string

[K+].[K+].Cl[Pt--](Cl)(Cl)Cl

InChI

1S/4ClH.2K.Pt/h4*1H;;;/q;;;;2*+1;+2/p-4

InChI key

RVRDLMCWUILSAH-UHFFFAOYSA-J

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General description

Potassium tetrachloroplatinate(II) is a ruby-red crystalline solid and can be prepared by reacting potassium hexachloroplatinate(IV) with cuprous chloride. It is mainly used as a reagent and inorganic catalyst in various chemical reactions. Its application includes the synthesis of other platinum compounds, organic transformations, and electroplating of metals. It is also a potential antitumor agent.

Application

Potassium tetrachloroplatinate(II) can be used as:
  • A precursor to synthesize CO-tolerant catalyst for hydrogen-air fuel cells.
  • An active and stable catalyst for selective methane oxidation.
  • As a starting material to synthesize high-performance Pt-based phosphorescent materials for electroluminescent devices.

Features and Benefits

Reacts with bis(dithiolates) to form metal-bis(dithiolates) with applications in laser Q-switch materials, liquid crystals, optical CD recording media, bar code materials and superconductivity. Reacts with capping polymers to form shape-control colloidal platinum nanoparticles for catalysis and photocatalysts.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

206075-5G:
206075-VAR:
206075-1G:
206075-BULK:


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Kyubin Shim et al.
Scientific reports, 9(1), 894-894 (2019-01-31)
Bimetallic nanoparticles (NPs) have aroused interest in various fields because of their synergetic and unique properties. Among those nanoparticles, we strategically approached and synthesized Au@Pt NPs via the sonochemical method with different molar ratios (e.g. 3:7, 5:5, and 7:3) of
Raj G
Advances in Inorganic Chemistry null
A Solution Phase Synthesis of Dendritic Platinum Nanoelectrocatalysts with the Assistance of Polyoxyethylene Nonylphenyl Ether.
Wang H, et al.
Journal of Inorganic and Organometallic Polymers and Materials, 25(2), 245-250 (2015)
Synthesis of shaped Pt nanoparticles using common anions or small molecules as shape-directing agents: observation of a strong halide or pseudo-halide effect.
Michel JA, et al.
Journal of Materials Chemistry, 3(5), 2012-2018 (2015)
The Biological Activity of Zeise's Salt and its Derivatives
Meieranz S, et al.
Angewandte Chemie (International Edition in English), 54(9), 2834-2837 (2015)

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