208671
Bis(triphenylphosphine)palladium(II) dichloride
98%
Synonym(s):
Dichlorobis(triphenylphosphine)palladium(II), Palladium(II)bis(triphenylphosphine) dichloride, PdCl2(PPh3)2
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About This Item
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Quality Level
Assay
98%
form
solid
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
SMILES string
Cl[Pd]Cl.c1(P(c2ccccc2)c3ccccc3)ccccc1.c4(P(c5ccccc5)c6ccccc6)ccccc4
InChI
1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
InChI key
YNHIGQDRGKUECZ-UHFFFAOYSA-L
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General description
Application
- Coupling of 2-iodoanisole and terminal alkynes to synthesize 2,3-disubstituted benzofurans.[2]
- Copper-free Sonogashira cross-coupling reaction to synthesize diphenylacetylene.[3]
- Regioselective hydrocarboxylation of styrene.[4]
- Negishi coupling of fluoroarylzinc pivalates to prepare fluorinated oligophenyls.[5]
- Coupling of iodo-α-β-unsaturated esters to afford tetrasubstituted olefins.[6]
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Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Chronic 4 - Skin Sens. 1A
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
JAN Code
208671-1G:
Q208671-BULK:
208671-25G:
208671-BULK:
208671-100G:
208671-500G:
208671-5G:
Q208671-VAR:
208671-VAR:
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A variety of transition-metal catalysts for the Suzuki coupling reaction are now available in our catalog. The majority of these catalysts are palladium- and nickelbased, typically utilizing phosphine-derived ligands.
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