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Documenti fondamentali

18514

Sigma-Aldrich

Kieselguhr

greener alternative

calcined, purified

Sinonimo/i:

Infusorial earth

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About This Item

Numero CAS:
Numero MDL:
Codice UNSPSC:
12000000
ID PubChem:

Stato

powder

Qualità

calcined, purified

Caratteristiche più verdi

Catalysis
Learn more about the Principles of Green Chemistry.

Impurezze

≤1% HCl solubles

Perdita

≤1% loss on ignition

Anioni in tracce

chloride (Cl-): ≤200 mg/kg
sulfate (SO42-): ≤500 mg/kg

Cationi in tracce

Fe: ≤500 mg/kg

Categoria alternativa più verde

Stringa SMILE

O=[Si]=O

InChI

1S/O2Si/c1-3-2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N

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Descrizione generale

Kieselguhr (diatomite, infusorial earth) is the fossilized skeletons of diatom algae. It is mainly made up of silica with many unique features like high porosity, small particle size, low density and thermal conductivity. It is primarily utilized as a source to manufacture filter aids, fire-bricks and adsorbents. Kieselguhr is the main component of the Berkefeld filter used for purifying water. It is also utilized in the filtration process of beer brewing.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Find details here.

Applicazioni

Kieselguhr (infusorial earth) may be used in the following processes:
  • Estimation of total fats.
  • As a catalyst in the synthesis of ketones and aldehydes via oxidation of corresponding oximes with manganese dioxide.
  • Green synthesis of β-nitroalkenes via Michael addition of 1,3-dicarbonyl compounds, by a grinding method in the absence of solvent and catalyst.
  • Preparation of KMnO4-kieselguhr reagent for use in the oxidation of primary alcohols to aldehydes with shorter reaction time.
Used for greener amide bond formation from amines and carboxylic acids after thermal activation at high temperature.

Clean, reusable and low cost heterogeneous catalyst for amide synthesis

Pittogrammi

Health hazard

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

STOT RE 1 Inhalation

Organi bersaglio

Lungs

Codice della classe di stoccaggio

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe di pericolosità dell'acqua (WGK)

nwg

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves


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Supelco

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Manufacture of ceramic bricks using recycled brewing spent Kieselguhr.
Ferraz E, et al.
Materials and Manufacturing Processes, 26(10), 1319-1329 (2011)
Oxidation of alcohols to carbonyl compounds with a new potassium permanganate adsorbed on kieselguhr reagent.
Lou J-D and Lou WX.
Synthetic Communications, 27(21), 3697-3699 (1997)
Household Water Treatment following Emergencies and Disasters- A Review
Gambhir RS, et al.
Indian Journal of Public Health Research & Development, 4(3), 249-252 (2013)
A method for the determination of the total fats of undried feces and other moist masses.
Saxon GJ.
The Journal of Biological Chemistry, 17, 99-102 (1914)
Characterization by Thermal Analysis of Natural Kieselguhr and Sand for Industrial Application.
Meradi H, et al.
Energy Procedia, 74, 1282-1288 (2015)

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