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443786

Sigma-Aldrich

Tetrachloroethylene

ACS reagent, ≥99.0%

Sinonimo/i:

PCE, Perchloroethylene

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About This Item

Formula condensata:
CCl2=CCl2
Numero CAS:
Peso molecolare:
165.83
Beilstein:
1361721
Numero CE:
Numero MDL:
Codice UNSPSC:
12352101
ID PubChem:
NACRES:
NA.04

Grado

ACS reagent

Livello qualitativo

Densità del vapore

5.83 (vs air)

Tensione di vapore

13 mmHg ( 20 °C)
19 mmHg ( 25 °C)

Saggio

≥99.0%

Forma fisica

liquid

tecniche

FTIR: suitable

Impurezze

≤0.05% water

Residuo dopo evaporazione

≤0.0005%

Colore

APHA: ≤10

Indice di rifrazione

n20/D 1.505 (lit.)

P. eboll.

121 °C (lit.)

Punto di fusione

−22 °C (lit.)

Solubilità

water: soluble 0.15 g/L at 25 °C

Densità

1.623 g/mL at 25 °C (lit.)

Stringa SMILE

Cl\C(Cl)=C(\Cl)Cl

InChI

1S/C2Cl4/c3-1(4)2(5)6
CYTYCFOTNPOANT-UHFFFAOYSA-N

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Descrizione generale

Tetrachloroethylene (perchloroethylene, PCE), is a chlorinated ethylene compound commonly used as a dry cleaning and degreasing solvent. It shows IR transparency as it has no C–H bonds making it an ideal solvent for IR spectroscopy. PCE is a man-made pollutant which is difficult to degrade. It is a ground water contaminant which has adverse effect on human health due to its potential toxicity and carcinogenicity. Some of the methods proposed for its degradation are Fenton oxidation treatment, reductive dehalogenation under methanogenic condition, and reduction using zero valent metal ions. One of the methods reported for its synthesis is by reacting ethylene dichloride and chlorine.

Applicazioni

Tetrachloroethylene may be used as a film-forming electrolyte additive in the manufacture of lithium ion batteries. It may also be used as an extractant for the estimation of oil and grease in water by Fourier transform infrared spectroscopy (FT-IR).

Avvertenze

Warning

Indicazioni di pericolo

Classi di pericolo

Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Organi bersaglio

Central nervous system

Codice della classe di stoccaggio

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

No data available

Punto d’infiammabilità (°C)

No data available


Certificati d'analisi (COA)

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Validation of a FT-IR method for the determination of oils and grease in water using tetrachloroethylene as the extraction solvent.
Farmaki E, et al.
Desalination, 210(1), 52-60 (2007)
Tetrachloroethylene as new film-forming additive to propylene carbonate-based electrolytes for lithium ion batteries with graphitic anode.
Hu Y, et al.
Solid State Ionics, 176(1), 53-56 (2005)
Decomposition of aqueous tetrachloroethylene by Fenton oxidation treatment.
Yoshida M, et al.
Water Science and Technology, 42(1-2), 203-208 (2000)
Robert DM and Murphy B.
Chlorinated Solvents: A Forensic Evaluation, 84-85 (2013)
D Ryoo et al.
Nature biotechnology, 18(7), 775-778 (2000-07-11)
Tetrachloroethylene (PCE) is thought to have no natural source, so it is one of the most difficult contaminants to degrade biologically. This common groundwater pollutant was thought completely nonbiodegradable in the presence of oxygen. Here we report that the wastewater

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