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76778

Supelco

Methyl acrylate

analytical standard

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About This Item

Formula condensata:
CH2=CHCOOCH3
Numero CAS:
96-33-3
Peso molecolare:
86.09
Beilstein:
605396
Numero CE:
202-500-6
Numero MDL:
MFCD00008627
Codice UNSPSC:
85151701
ID PubChem:
329767338
NACRES:
NA.24

Grado

analytical standard

Livello qualitativo

100

Densità del vapore

3 (vs air)

Tensione di vapore

67.5 mmHg ( 20 °C)

Saggio

≥99.5% (GC)

Temp. autoaccensione

874 °F

Durata

limited shelf life, expiry date on the label

contiene

~0.0015% hydroquinone monomethyl ether as stabilizer

Limite di esplosione

14.5 %

tecniche

HPLC: suitable
gas chromatography (GC): suitable

Indice di rifrazione

n20/D 1.402 (lit.)
n20/D 1.403

P. eboll.

80 °C (lit.)

Punto di fusione

−75 °C (lit.)

Densità

0.956 g/mL at 25 °C (lit.)

applicazioni

environmental
petroleum

Formato

neat

Stringa SMILE

COC(=O)C=C

InChI

1S/C4H6O2/c1-3-4(5)6-2/h3H,1H2,2H3
BAPJBEWLBFYGME-UHFFFAOYSA-N

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Descrizione generale

This substance is listed on the positive list of the EU regulation 10/2011 for plastics intended to come into contact with food.

Applicazioni

Methyl acrylate can undergo transesterification reaction with 1-butanol under thermal conditions in the presence of hydrochloric acid to yield butyl acrylate as the major product.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Prodotti consigliati

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Pittogrammi

FlameSkull and crossbones
GHS02,GHS06

Avvertenze

Danger

Classi di pericolo

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

27.0 °F - closed cup

Punto d’infiammabilità (°C)

-2.8 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
BCCF4354
BCBZ8471
BCBS5876V
BCBR1099V
BCBL3504V

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Organic Chemistry (2008)
María B Blanco et al.
Environmental science & technology, 44(18), 7031-7036 (2010-08-24)
A product study is reported on the gas-phase reactions of OH radicals and Cl atoms with methyl acrylate. The experiments were performed in a 1080-L quartz-glass chamber in synthetic air at 298 ± 2 K and 760 ± 10 Torr
Enqi Jin et al.
Journal of agricultural and food chemistry, 59(5), 1729-1738 (2011-02-10)
Inexpensive and biodegradable thermoplastics were developed through graft polymerization of native chicken feather with methyl acrylate as a potential substitute for petroleum products. Poultry feathers are available in large quantities at a low price. However, natural chicken feathers have poor
Boris Neuwald et al.
Journal of the American Chemical Society, 135(3), 1026-1036 (2012-12-22)
Various phosphinesulfonato ligands and the corresponding palladium complexes [{((P^O)PdMeCl)-μ-M}(n)] ([{((X)1-Cl)-μ-M}(n)], (P^O) = κ(2)-P,O-Ar(2)PC(6)H(4)SO(2)O) with symmetric (Ar = 2-MeOC(6)H(4), 2-CF(3)C(6)H(4), 2,6-(MeO)(2)C(6)H(3), 2,6-(iPrO)(2)C(6)H(3), 2-(2',6'-(MeO)(2)C(6)H(3))C(6)H(4)) and asymmetric substituted phosphorus atoms (Ar(1) = 2,6-(MeO)(2)C(6)H(3), Ar(2) = 2'-(2,6-(MeO)(2)C(6)H(3))C(6)H(4); Ar(1) = 2,6-(MeO)(2)C(6)H(3), Ar(2) = 2-cHexOC(6)H(4)) were
Takafumi Yukawa et al.
Journal of the American Chemical Society, 132(34), 11988-11992 (2010-08-10)
The catalytic asymmetric aza-Morita-Baylis-Hillman reaction using unactivated methyl acrylate is described. A simple Lewis acidic metal catalyst, such as La(OTf)(3), was not suitable for the reaction, but rare earth metal alkoxide/linked-BINOL complexes possessing bifunctional Lewis acid and Brønsted base properties
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