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Supelco

Magnesium matrix modifier

for graphite furnace-AAS

Sinonimo/i:

Magnesium nitrate – nitric acid solution, Magnesium modifier

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About This Item

Numero CAS:
13446-18-9
Beilstein:
4948473
Numero MDL:
MFCD00085308
Codice UNSPSC:
12000000
eCl@ss:
32129211
ID PubChem:
329759765
NACRES:
NA.21

Grado

for graphite furnace-AAS

Livello qualitativo

100

PM

Mr 256.41 g/mol

Concentrazione

10.0 g/L±0.3 g/L Mg (in ~17% nitric acid)

Cationi in tracce

Ag: ≤0.001 mg/kg
As: ≤0.01 mg/kg
Cd: ≤0.001 mg/kg
Pb: ≤0.01 mg/kg
Se: ≤0.1 mg/kg
Tl: ≤0.01 mg/kg

InChI

1S/Mg
FYYHWMGAXLPEAU-UHFFFAOYSA-N

Descrizione generale

Matrix modification is a procedure for reducing volatilization and vapour-phase intrusions using a chemical reagent which acts as buffer enabling the use of higher pre-treated and atomization temperatures. The reagent causes either the interfering component to become more volatile or the analyte is converted to less volatile form. Magnesium is a first class modifier, forming oxides in the graphite furnace during heat pre-treatment. Magnesium added as nitrate has high thermal stability.

Applicazioni

Magnesium along with palladium may be used as matrix modifier during platform atomization, to determine lead in solution and in soil slurries, using electrothermal atomization atomic absorption spectrometry. It may also be used for determining brain manganese concentrations during graphite furnace atomic absorption spectrometry (GFAAS).

Avvertenze

Danger

Indicazioni di pericolo

H272,H290,H314,H332

Classi di pericolo

Acute Tox. 4 Inhalation - Eye Dam. 1 - Met. Corr. 1 - Ox. Liq. 3 - Skin Corr. 1B

Rischi supp

EUH071

Codice della classe di stoccaggio

5.1B - Oxidizing hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
BCCF3860
BCCB8361
BCBW1971
BCBS0087V
BCBR3446V

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Effectiveness of palladium plus magnesium as a matrix modifier for the determination of lead in solutions and soil slurries by electrothermal atomisation atomic absorption spectrometry.
Hinds, Michael W., Mohan Katyal, and Kenneth W. Jackson.
Journal of Analytical Atomic Spectrometry, 3, 83-87 (1988)
Lauri H. J. Lajunen, P. Peramaki
Spectrochemical Analysis by Atomic Absorption and Emission, 142-144 (2004)
Magnesium nitrate as a matrix modifier in the stabilized temperature platform furnace
W. Slavin, G. R. Carnrick, and D. C. Manning
Analytical Chemistry, 54, 621-624 (1982)
Dinamene Santos et al.
Biological trace element research, 150(1-3), 337-341 (2012-09-14)
Manganese (Mn) is an essential element and it acts as a cofactor for a number of enzymatic reactions, including those involved in amino acid, lipid, protein, and carbohydrate metabolism. Excessive exposure to Mn can lead to poisoning, characterized by psychiatric
Zhichao Liu et al.
PLoS computational biology, 7(12), e1002310-e1002310 (2011-12-24)
Drug-induced liver injury (DILI) is a significant concern in drug development due to the poor concordance between preclinical and clinical findings of liver toxicity. We hypothesized that the DILI types (hepatotoxic side effects) seen in the clinic can be translated

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