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44920

Sigma-Aldrich

Iron(III) acetylacetonate

purum, ≥97.0% (RT)

Sinonimo/i:

2,4-Pentanedione iron(III) derivative, Fe(acac)3, Ferric acetylacetonate, Iron(III) 2,4-pentanedionate

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About This Item

Formula condensata:
Fe(C5H7O2)3
Numero CAS:
14024-18-1
Peso molecolare:
353.17
Beilstein:
4157960
Numero CE:
237-853-5
Numero MDL:
MFCD00000020
Codice UNSPSC:
12352103
ID PubChem:
329756564
NACRES:
NA.23

Grado

purum

Livello qualitativo

200

Saggio

≥97.0% (RT)

Forma fisica

powder

Impiego in reazioni chimiche

core: iron
reagent type: catalyst

Punto di fusione

180-182 °C (dec.) (lit.)
180-190 °C (dec.)

Densità

5.24 g/mL at 25 °C (lit.)

Stringa SMILE

CC(=O)\C=C(\C)O[Fe](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;
AQBLLJNPHDIAPN-LNTINUHCSA-K

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Descrizione generale

Iron(III) acetylacetonate, also known as tris(acetylacetonato)iron(III) or Fe(acac)3, is a coordination compound that is highly soluble in organic solvents. It is used as a precursor in the preparation of iron-containing materials and thin films, which are important in electronics and coatings. Additionally, it is also as a catalyst in organic reactions, particularly in the synthesis of organic compounds and polymerization processes.

Applicazioni

Iron(III) acetylacetonate can be used as:     
  • A precursor in the synthesis of Fe3O4/carbon composite fibers via forcespinning. This fiber material is suitable for use as anode materials in lithium-ion batteries.     
  • A precursor in the synthesis of iron-based metal-organic frameworks (MOFs) for the applications in rechargeable alkali-ion batteries.
  • A catalyst in the controlled living radical polymerization of vinyl acetate to synthesis of polymers with controlled molecular weights.   
  • A precursor to synthesize iron-doped titania (Fe-TiO2) photocatalysts for the potential applications in photocatalytic reactions.     
  • A MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.

MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.

Altre note

Catalyst used in Grignard reactions with acid chlorides to give ketones

Pittogrammi

CorrosionExclamation mark
GHS05,GHS07

Avvertenze

Danger

Indicazioni di pericolo

H302 + H312 + H332,H318

Classi di pericolo

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves

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Certificati d'analisi (COA)

Lot/Batch Number
BCCB3470
BCBV4183
BCBT5666
BCBS5090V
BCBR4648V

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Sigma-Aldrich

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Oleilammina ≥98% (primary amine)

SAFC

HT-OA100

Oleilammina

Nickel(II) acetylacetonate 95%

Sigma-Aldrich

283657

Nickel(II) acetylacetonate

Oleilammina technical grade, 70%

Sigma-Aldrich

O7805

Oleilammina

Cobalt(III) acetylacetonate 99.99% trace metals basis

Sigma-Aldrich

494534

Cobalt(III) acetylacetonate

Cobalt(II) acetylacetonate 97%

Sigma-Aldrich

227129

Cobalt(II) acetylacetonate

Cloruro di ferro(III) reagent grade, ≥98%, chunks

Sigma-Aldrich

F2877

Cloruro di ferro(III)

V. Fiandanese et al.
Tetrahedron Letters, 25, 4805-4805 (1984)
C. Cardellicchio et al.
Tetrahedron Letters, 28, 2053-2053 (1987)
Roland Schoch et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 15(17), 3768-3775 (2014-09-13)
A new iron-based catalyst for carbon monoxide oxidation, as a potential substitute for precious-metal systems, has been prepared by using a facile impregnation method with iron tris-acetylacetonate as a precursor on γ-Al2 O3 . Light-off and full conversion temperatures as
Tingting Li et al.
Nanoscale, 7(9), 4171-4178 (2015-02-12)
The excellent electrochemical performance of greigite (Fe3S4) coupled with its vast abundance and low toxicity make it a good prospect as an anode material for lithium ion batteries (LIBs). In this research, a simple and feasible approach for producing pure
Michael Challenor et al.
Dalton transactions (Cambridge, England : 2003), 43(44), 16780-16787 (2014-10-07)
We report the synthesis, characterisation and evaluation of the in vitro biocompatibility of polymeric nanoparticles with both magnetic and upconverting fluorescent properties. The particles consist of superparamagnetic iron oxide nanoparticles and upconverting NaYF4:Yb,Er nanoparticles co-encapsulated within a poly(glycidyl methacrylate) sphere.
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