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Sigma-Aldrich

1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

≥97.0% (NMR)

Sinonimo/i:

EMIM BTI, EMIM TFSI, EMIMIm

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About This Item

Formula empirica (notazione di Hill):
C8H11F6N3O4S2
Numero CAS:
Peso molecolare:
391.31
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.22

Livello qualitativo

Saggio

≥97.0% (NMR)

Forma fisica

liquid

Impurezze

<0.5% water

Punto di fusione

≥−15 °C (lit.)

Gruppo funzionale

fluoro

Stringa SMILE

CCn1cc[n+](C)c1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F

InChI

1S/C6H11N2.C2F6NO4S2/c1-3-8-5-4-7(2)6-8;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h4-6H,3H2,1-2H3;/q+1;-1
LRESCJAINPKJTO-UHFFFAOYSA-N

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Descrizione generale

1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [EMIM][N(Tf)2] is a room temperature ionic liquid (RTIL). ([EMIM][N(Tf)2]) as a non-aqueous solvent, is advantageous over traditional aprotic polar organic solvents in electrochemical investigation of electroactive species since it has low vapor pressure, high thermal stability, good conductivity and a wide electrochemical window. [EMIM][N(Tf)2] shows good solubility in CO2.

Applicazioni

[EMIM][N(Tf)2] may be used as a green solvent for the synthesis of zinc oxide (ZnO) nanoparticles under microwave conditions. It is useful in reactions which need a solvent with high CO2 solubility.

Stato fisico

fluorinated, hydrophobic ionic liquid

Altre note

Enantioselective reactions in ionic liquids

Note legali

Product protected by U.S. Patent 5,827,602 assigned to Covalent Associates, Inc. Woburn, Ma, USA

Pittogrammi

Skull and crossbones

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 3 Oral

Codice della classe di stoccaggio

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe di pericolosità dell'acqua (WGK)

WGK 1

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Voltammetry of oxygen in the room-temperature ionic liquids 1-ethyl-3-methylimidazolium bis ((trifluoromethyl) sulfonyl) imide and hexyltriethylammonium bis ((trifluoromethyl) sulfonyl) imide: one-electron reduction to form superoxide. Steady-state and transient behavior in the same cyclic voltammogram resulting from widely different diffusion coefficients of oxygen and superoxide
Buzzeo, Marisa C., et al.
The Journal of Physical Chemistry A, 107.42, 8872-8878 (2003)
Thermodynamic properties of mixtures containing ionic liquids. 3. Liquid? liquid equilibria of binary mixtures of 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide with propan-1-ol, butan-1-ol, and pentan-1-ol
Heintz, Andreas, Jochen K. Lehmann, and Christiane Wertz
Journal of Chemical and Engineering Data, 48.3, 472-474 (2003)
Solubility of carbon dioxide in the ionic liquid 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide.
Schilderman AM, et al
Fluid Phase Equilibria, 260(1), 19-22 (2007)
Determination of ammonia based on the electro-oxidation of hydroquinone in dimethylformamide or in the room temperature ionic liquid, 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide.
Giovanelli D, et al.
Talanta, 62(5), 904-911 (2004)
Liquid structure of room-temperature ionic liquid, 1-ethyl-3-methylimidazolium bis-(trifluoromethanesulfonyl) imide.
Fujii K, et al.
The Journal of Physical Chemistry B, 112(14), 4329-4336 (2008)

Articoli

Ionic Liquids for Electrochemical Applications

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