1.13364

Tetrahydrofuran-d₈

deuteration degree min 99.5% for NMR spectroscopy MagniSolv^™

• Sinonimo/i: THF deuterated, Deuterated tetrahydrofuran, Octadeuterotetrahydrofuran
• Formula empirica (notazione di Hill): C₄D₈O
• Numero CAS: 1693-74-9
• Peso molecolare: 80.16
• Beilstein: 111854
• Numero MDL: MFCD00044238
• Codice UNSPSC: 12142201
• Numero indice EU: 216-898-4
• NACRES: NA.22

Proprietà

• Livello qualitativo: 200
• Forma fisica: liquid
• Temp. autoaccensione: 215 °C
• Potenza: 1650 mg/kg LD₅₀, oral (Rat)
• tecniche: NMR: suitable
• Impurezze: ≤0.030% Water (H<SUB>2</SUB>O) (NMR); ≤0.050% Water (H<SUB>2</SUB>O) (Karl Fischer)
• Indice di rifrazione: n20/D 1.403 (lit.)
• P. eboll.: 65-66 °C (lit.)
• Punto di fusione: −106 °C (lit.)
• Temp. transizione: flash point -17.5 °C
• Densità: 0.985 g/mL at 25 °C (lit.)
• Spostamento di massa: M+8
• Temperatura di conservazione: 2-8°C
• Stringa SMILE: [2H]C1([2H])OC([2H])([2H])C([2H])([2H])C1([2H])[2H]
• InChI: 1S/C4H8O/c1-2-4-5-3-1/h1-4H2/i1D2,2D2,3D2,4D2; WYURNTSHIVDZCO-SVYQBANQSA-N

Descrizione

Descrizione generale

A wide range of MagniSolv deuterated solvents with extremely low residual water, excellent chemical purity, and the highest isotopic enrichment available can satisfy the most demanding requirements of researchers. Depending on application and sensitivity of the NMR spectrometer our offer solvents with deuteration degrees between 98% and 99.96%. In case of all the water soluble deuterated standard products, water content is specified according to both Karl Fischer and NMR.

Applicazioni

• Experimental and Theoretical Study of CO2 Insertion into Ruthenium Hydride Complexes.: This research provides insights into the mechanistic pathways for CO2 reactivity with ruthenium hydride complexes, potentially relevant for catalytic applications including transformations involving Tetrahydrofuran-d₈ (Ramakrishnan et al., 2016).



• Syntheses, structures, and NMR chemical shifts of a family of trimethyltin alkoxide, amide, halide and cyclopentadienyl compounds.: Details the synthesis and structural characterization of trimethyltin compounds, useful for understanding the coordination chemistry that may involve Tetrahydrofuran-d₈ as a solvent or structural analogue (Lichtscheidl et al., 2015).



• NMR studies of coupled low- and high-barrier hydrogen bonds in pyridoxal-5′-phosphate model systems in polar solution.: Discusses the application of NMR spectroscopy in studying hydrogen bonding interactions, where Tetrahydrofuran-d₈ could be utilized as a deuterated solvent for enhanced spectral clarity (Sharif et al., 2007).



• Stable hydrocarbon diradical, an analogue of trimethylenemethane.: Investigates stable hydrocarbon diradicals, where Tetrahydrofuran-d₈ may be used as part of the experimental setup to stabilize reactive intermediates or as a solvent to study radical stability (Rajca et al., 2005).

Risultati analitici

Deuteration degree: ≥ 99.50 %
Water (NMR, H₂O): ≤ 0.030 %
Performance test (NMR-spectrum): passes test
Water (K. Fischer, H₂O + D₂O): ≤ 0.050 %

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Note legali

MAGNISOLV is a trademark of Merck KGaA, Darmstadt, Germany

Informazioni sulla sicurezza

• Pittogrammi: GHS02,GHS07,GHS08
• Avvertenze: Danger
• Indicazioni di pericolo: H225 - H302 - H319 - H335 - H336 - H351
• Consigli di prudenza: P202 - P210 - P233 - P301 + P312 - P305 + P351 + P338 - P308 + P313
• Classi di pericolo: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2
• Rischi supp: EUH019
• Codice della classe di stoccaggio: 3 - Flammable liquids
• Classe di pericolosità dell'acqua (WGK): WGK 1
• Punto d’infiammabilità (°F): 1.4 °F - closed cup
• Punto d’infiammabilità (°C): -17 °C - closed cup