ALD00378

Wasa-Yu MPAA Ligand

• Sinonimo/i: (S)-3-(2,6-Difluorophenyl)-2-((((4-(trichloromethyl)heptan-4- yl)oxy)carbonyl)amino)propanoic acid
• Formula empirica (notazione di Hill): C₁₈H₂₂Cl₃F₂NO₄
• Numero CAS: 1346641-35-7
• Peso molecolare: 460.73
• Codice UNSPSC: 12352101
• ID PubChem: 329772660
• NACRES: NA.22

Proprietà

• Forma fisica: solid
• Impiego in reazioni chimiche: reaction type: C-H Activation; reagent type: catalyst; reagent type: ligand; reaction type: Peptide Synthesis
• P. eboll.: 521.1 °C±50.0 °C
• Densità: 1.365 g/cm³±0.06 g/cm³
• Gruppo funzionale: amine; carboxylic acid
• Temperatura di conservazione: 2-8°C
• Stringa SMILE: O=C(O)[C@@H](NC(OC(CCC)(CCC)C(Cl)(Cl)Cl)=O)CC1=C(F)C=CC=C1F
• InChI: 1S/C18H22Cl3F2NO4/c1-3-8-17(9-4-2,18(19,20)21)28-16(27)24-14(15(25)26)10-11-12(22)6-5-7-13(11)23/h5-7,14H,3-4,8-10H2,1-2H3,(H,24,27)(H,25,26)/t14-/m0/s1; MYNBDMWXOQDYED-AWEZNQCLSA-N

Descrizione

Applicazioni

The Wasa-Yu MPAA Ligand has been reported by Yu and coworkers to promote the enantioselective C-H activation of cyclopropanes. This transformation is carried out through the coupling of organoboron reagents using palladium-mediated catalysis.

Altre note

Pd(II)-Catalyzed Enantioselective C–H Activation of Cyclopropanes

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable