75920

OXONE^® tetrabutylammonium salt

technical, ~1.6% active oxygen basis

• Sinonimo/i: Tetrabutylammonium OXONE^®, Tetrabutylammonium hydrogen monopersulfate, Tetrabutylammonium peroxomonosulfate, Tetrabutylammonium persulfate triple salt
• Numero CAS: 104548-30-3
• Beilstein: 5199887
• Numero MDL: MFCD20503057
• Codice UNSPSC: 12352000
• ID PubChem: 24886893
• NACRES: NA.22

Proprietà

• Grado: technical
• Stato: powder
• Impiego in reazioni chimiche: reagent type: oxidant
• Concentrazione: ~1.6% (active oxygen)
• Punto di fusione: 144-146 °C
• Stringa SMILE: OS([O-])(=O)=O.[O-]S([O-])(=O)=O.OS(=O)(=O)O[O-].OS(=O)(=O)O[O-].CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC
• InChI: 1S/5C16H36N.2H2O5S.2H2O4S/c5*1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2*1-5-6(2,3)4;2*1-5(2,3)4/h5*5-16H2,1-4H3;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5; IGMBKNUVZFAHJM-UHFFFAOYSA-I

Descrizione

Applicazioni

Reagent for:

• Oxidation of Hantzsch 1,4-Dihydropyridines catalyzed by manganese(III) Schiff Base complexes
• Epoxidation of alkenes
• Oxidation of sulfides and olefins
• Oxidation of alcohols
• Oxidation of aromatic amines for synthesis of azoxy arenes

Altre note

Form of Oxone specially suited for the oxidation of sensitive compounds in CH₂Cl₂; Reagent for preparing 2-tetrahydrofuranyl ethers from alcohols and THF by radical coupling

Note legali

OXONE is a registered trademark of E. I. du Pont de Nemours and Company

Informazioni sulla sicurezza

• Pittogrammi: GHS05,GHS07
• Avvertenze: Danger
• Indicazioni di pericolo: H302,H314
• Consigli di prudenza: P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Classi di pericolo: Acute Tox. 4 Oral - Skin Corr. 1B
• Codice della classe di stoccaggio: 8A - Combustible corrosive hazardous materials
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable
• Dispositivi di protezione individuale: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges