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540250

Sigma-Aldrich

(S)-(+)-1,2-Propanediol

96%

Sinonimo/i:

(S)-(+)-Propylene glycerol

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About This Item

Formula condensata:
CH3CH(OH)CH2OH
Numero CAS:
Peso molecolare:
76.09
Beilstein:
1718871
Numero MDL:
Codice UNSPSC:
12352001
ID PubChem:
NACRES:
NA.22

Saggio

96%

Attività ottica

[α]20/D +16.5°, neat

Purezza ottica

ee: 98% (GLC)

Indice di rifrazione

n20/D 1.432 (lit.)

P. ebollizione

186-188 °C/765 mmHg (lit.)

Densità

1.036 g/mL at 20 °C (lit.)

Gruppo funzionale

hydroxyl

Stringa SMILE

C[C@H](O)CO

InChI

1S/C3H8O2/c1-3(5)2-4/h3-5H,2H2,1H3/t3-/m0/s1
DNIAPMSPPWPWGF-VKHMYHEASA-N

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Applicazioni

(S)-(+)-1,2-Propanediol can be used as a reactant to synthesize:
  • Optically active chiral (S)-1, 2-propanediol derivatives using mesogenic carboxylic acids via esterification in the presence of dimethylaminopyridine (DMAP) as a catalyst.
  • 3,4-Ethylenedioxythiophenes via Mitsunobu reaction.
  • Vicinal diol cyclic sulfates in the presence of sodium periodate and ruthenium chloride as catalysts.

Applicazioni

Codice della classe di stoccaggio

10 - Combustible liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

217.4 °F - closed cup

Punto d’infiammabilità (°C)

103 °C - closed cup


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