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Documenti fondamentali

510831

Sigma-Aldrich

Poly(3-octylthiophene-2,5-diyl)

regiorandom

Sinonimo/i:

P3OT

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About This Item

Formula condensata:
(C12H18S)n
Numero CAS:
Numero MDL:
Codice UNSPSC:
12352103
NACRES:
NA.23

PM

average Mn 22,000
average Mw 36,600

Colore

red

Punto di fusione

198-211 °C

Solubilità

chloroform, methylene chloride, toluene, and THF: soluble

Fluorescenza

λex 419 nm; λem 550 nm in chloroform

Prestazioni di un dispositivo OPV

ITO/PEDOT:PSS/P3OT:PC61BM (1:2)/LiF/Al

  • Short-circuit current density (Jsc): 5.55 mA/cm2
  • Open-circuit voltage (Voc): 0.5 V
  • Fill Factor (FF): 0.33
  • Power Conversion Efficiency (PCE): 0.91 %

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Descrizione generale

Poly(3-alkylthiophene)s exhibit thermo- and solvatochromism. Regiorandom poly(3-octylthiophene) shows relatively weak red PL in dilute solution. The emission is largely quenched in concentrated solutions and solid thin films.1:1 (head-to-head):(head-to-tail) linkages of regioisomers.
Poly(3-octylthiophene-2,5-diyl) (P3OT) is an alkylthiophene based conductive polymer with high electroluminescence. It is soluble in most of the organic solvents and can be prepared by the electrochemical polymerization of 3-octylthiophene (3OT). It has hydrophobic properties and can be used as a transducer for ion selective electrodes.

Applicazioni

P3OT forms a nanocomposite with carbon nanotubes (CNTs) for devising a high performance semiconducting material. It can also be used as a π-conjugating polymer for the fabrication of organic electronic based devices which include polymeric diodes, solar cells and photovoltaic modules.
Conducting polymer.
Rechargeable battery electrodes, electrochromic devices, chemical and optical sensors, light-emitting diodes, microelectrical amplifiers, field-effect transistors and non-linear optical materials.
Used in organic field-effect transistors and in polymer-based solar cells.

Caratteristiche e vantaggi

Good processability, environmental stability and electroactivity.

Confezionamento

Packaged in glass bottles

Note legali

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Gloves, type N95 (US)


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Semiconducting polymer diodes: Large size, low cost photodetectors with excellent visible-ultraviolet sensitivity
Yu, G and Pakbaz, K and Heeger, AJ
Applied Physics Letters, 64(25), 3422-3424 (1994)
Physical characterizations of semi-conducting conjugated polymer-CNTs nanocomposites
Abu-Abdeen M, et al.
Journal of Polymer Research, 19(3), 9839-9839 (2012)
Light-Emitting Polymers
Pei Q, et al.
Material Matters, 2(3), 26-26 (2007)
Structural analysis of poly (3-alkylthiophene) s
Leclerc M, et al.
Die Makromolekulare Chemie, 190(12), 3105-3116 (1989)
Single-wall carbon nanotube/conjugated polymer photovoltaic devices
Kymakis E and Amaratunga G
Applied Physics Letters, 80(1), 112-114 (2002)

Articoli

Light-Emitting Polymers

Intrinsically stretchable active layers for organic field-effect transistors (OFET) are discussed. Polymer structural modification & post-polymerization modifications are 2 methods to achieve this.

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