467448

Triethylsilane

97%

• Sinonimo/i: NSC 93579, Triethylhydrosilane, Triethylsilicon hydride
• Formula condensata: (C₂H₅)₃SiH
• Numero CAS: 617-86-7
• Peso molecolare: 116.28
• Beilstein: 1098278
• Numero CE: 210-535-3
• Numero MDL: MFCD00009018
• Codice UNSPSC: 12352103
• ID PubChem: 24870410
• NACRES: NA.22

Proprietà

• Livello qualitativo: 200
• Saggio: 97%
• Impiego in reazioni chimiche: reagent type: reductant
• Indice di rifrazione: n20/D 1.412 (lit.)
• P. eboll.: 107-108 °C (lit.)
• Densità: 0.728 g/mL at 25 °C (lit.)
• Stringa SMILE: CC[SiH](CC)CC
• InChI: 1S/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3; AQRLNPVMDITEJU-UHFFFAOYSA-N

Descrizione

Applicazioni

Catalyst for:

• Synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain
• Redox initiated cationic polymerization
• Beckmann rearrangement of cyclododecanone oxime
• Regioselective reductive coupling of enones and allenes

Catalyst reactivation after catalyst polymerization of styrene

Studies involving the prediction of organosilicon flash points

Triethylsilane can be used as:

• A reducing agent in the regioselective reductive coupling of enones and allenes.
• A reagent in the redox initiated cationic polymerization.
• A reagent in catalytic transfer hydrogenation, reduction of alkyl halides and silylation of aromatic C-H bonds, etc.
• As a reagent for the generation of indium hydride (Cl2InH) applicable as a catalyst for the intramolecular cyclization of enynes.

Informazioni sulla sicurezza

• Pittogrammi: GHS02,GHS07
• Avvertenze: Danger
• Indicazioni di pericolo: H225,H315,H319,H335
• Consigli di prudenza: P210 - P302 + P352 - P305 + P351 + P338
• Classi di pericolo: Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
• Organi bersaglio: Respiratory system
• Codice della classe di stoccaggio: 3 - Flammable liquids
• Classe di pericolosità dell'acqua (WGK): WGK 2
• Punto d’infiammabilità (°F): 21.2 °F
• Punto d’infiammabilità (°C): -6 °C
• Dispositivi di protezione individuale: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter