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43961

Sigma-Aldrich

1-Allyl-3-methylimidazolium chloride

greener alternative

≥97.0% (HPLC)

Sinonimo/i:

AMIM-Cl

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About This Item

Formula empirica (notazione di Hill):
C7H11ClN2
Numero CAS:
Peso molecolare:
158.63
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.22

Livello qualitativo

Saggio

≥97.0% (HPLC)

Stato

crystals

Caratteristiche più verdi

Safer Solvents and Auxiliaries
Catalysis
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sustainability

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Categoria alternativa più verde

Temperatura di conservazione

−20°C

Stringa SMILE

[Cl-].C[n+]1ccn(CC=C)c1

InChI

1S/C7H11N2.ClH/c1-3-4-9-6-5-8(2)7-9;/h3,5-7H,1,4H2,2H3;1H/q+1;/p-1
QVRCRKLLQYOIKY-UHFFFAOYSA-M

Descrizione generale

1-Allyl-3-methylimidazolium chloride is a thermostable and nonvolatile task-specific ionic liquid (TSIL). It shows high cellulose solubilization ability.
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Applicazioni

AMIM-Cl may be used:
  • As a solvent to dissolve cellulose during the preparation of regenerated cellulose materials.
  • As a solvent for the acetylation of cornhusk cellulose to form cornhusk cellulose acetates (CCAs).
  • As a plasticizer for cornstarch to form AMIM-Cl-plasticized starch film.

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves


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Certificati d'analisi (COA)

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Tosylation and acylation of cellulose in 1-allyl-3-methylimidazolium chloride.
Granstrom M, et al.
Cellulose, 15(3), 481-488 (2008)
Ganeswar Sahu et al.
Polymers, 12(2) (2020-02-13)
This paper presents the dielectric characteristics of nanocomposite films of poly(vinyl alcohol) (PVA) embedded with silver (Ag) nanoparticles and graphene oxide(GO). The nanocomposite films were fabricated by using the solvent casting approach. The morphological analysis was carried out through scanning
Acetone-soluble cellulose acetates prepared by one-step homogeneous acetylation of cornhusk cellulose in an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl).
Cao Y, et al.
Carbohydrate Polymers, 69(4), 665-672 (2007)
1-Allyl-3-methylimidazolium chloride plasticized-corn starch as solid biopolymer electrolytes.
Ning W, et al.
Carbohydrate Polymers, 76(3), 482-484 (2009)
Ashna Rajeev et al.
Soft matter, 14(37), 7615-7624 (2018-08-31)
Water added to a solution of microcrystalline cellulose (MCC) in 1-allyl-3-methylimidazolium chloride (AmimCl) reduces the solvent quality and causes significant changes in the flow properties and microstructure due to restructuring and aggregation of cellulose molecules. We report an experimental investigation

Articoli

Task-Specific Ionic Liquids (TSILs) for the selective liquid/liquid extraction of heavy metals from aqueous systems were first published by Robin D. Rogers et al. in the year 2001.

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