392278
6-Bromohexanenitrile
95%
Sinonimo/i:
5-Bromopentyl cyanide, 6-Bromocapronitrile
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About This Item
Formula condensata:
Br(CH2)5CN
Numero CAS:
Peso molecolare:
176.05
Numero CE:
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.22
Prodotti consigliati
Saggio
95%
Stato
liquid
Indice di rifrazione
n20/D 1.477 (lit.)
P. ebollizione
134 °C/13 mmHg (lit.)
Densità
1.328 g/mL at 25 °C (lit.)
Gruppo funzionale
bromo
nitrile
Stringa SMILE
BrCCCCCC#N
InChI
1S/C6H10BrN/c7-5-3-1-2-4-6-8/h1-5H2
PHOSWLARCIBBJZ-UHFFFAOYSA-N
Descrizione generale
6-Bromohexanenitrile (6-Bromohexanonitrile) is an ω-bromoalkanonitrile. Friedel Crafts alkylation of 6-bromohexanenitrile with benzene has been studied.
Applicazioni
6-Bromohexanenitrile (6-Bromocapronitrile, 6-Bromohexanonitrile) is suitable reagent used in the synthesis of (5-cyanopentyl)zinc(II) bromide, an organozinc reagent. It may be used in the synthesis of the following:
- 6-(1,4-dioxa-8-azaspiro[4.5]dec-8-yl)hexanenitrile.
- dimethyl 6,6′-dithiobiscaproimidate, a long-chain dithiobisimidate.
- N-benzyloxy-(4-cyanopentyl)-carbamic acid ethyl ester, a N-benzyloxy carbamate derivative.
- 1-hetarylsulfanyl-ω-cyanoalkanes.
Avvertenze
Warning
Indicazioni di pericolo
Consigli di prudenza
Classi di pericolo
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Organi bersaglio
Respiratory system
Codice della classe di stoccaggio
10 - Combustible liquids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
235.4 °F - closed cup
Punto d’infiammabilità (°C)
113 °C - closed cup
Dispositivi di protezione individuale
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Friedel-Crafts alkylation of benzene by normal ?-chloroalkanoic acids and their methyl esters and nitriles.
Zakharkin LI and Anikina EV
Bulletin of the Academy of Sciences of the USSR, Division of chemical science, 36(2), 327-330 (1987)
H Peretz et al.
European journal of biochemistry, 63(1), 77-82 (1976-03-16)
This communication describes a simple method for synthesizing cleavable bifunctional imido esters of different chain lengths. These reagents, which form covalent crosslinks between lysine residues of proteins, contain a disulfide bond which is cleaved under mild conditions by reducing agents
?Green Chemical" Methods for the Regioselective Synthesis of 1-Hetarylsulfanyl-?-Cyanoalkanes."
Abele E, et al.
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NICKEL-CATALYZED ENANTIOSELECTIVE NEGISHI CROSS-COUPLINGS OF RACEMIC SECONDARY α-BROMO AMIDES WITH ALKYLZINC REAGENTS: (S)-N-BENZYL-7-CYANO-2-ETHYL-N-PHENYLHEPTANAMIDE.
Sha Lou et al.
Organic syntheses; an annual publication of satisfactory methods for the preparation of organic chemicals, 87, 330-330 (2010-01-01)
Yuan Liu et al.
Tetrahedron, 67(12), 2206-2214 (2011-04-19)
N-Alkyl-N-benzyloxy carbamates, 2, undergo facile intramolecular cyclization with a variety of carbon nucleophiles to give functionalized 5- and 6-membered protected cyclic hydroxamic acids, 3, in good to excellent yields. This method can be extended to prepare seven-membered cyclic hydroxamic acids
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