335363

[1,3-Bis(diphenylphosphino)propane]dichloronickel(II)

• Sinonimo/i: (1,3-dppp)NiCl₂, 1,3-Bis(diphenylphosphino)propane nickel(II) chloride, Ni(dppp)Cl₂
• Formula condensata: [(C₆H₅)₂P(CH₂)₃P(C₆H₅)₂]NiCl₂
• Numero CAS: 15629-92-2
• Peso molecolare: 542.04
• Numero MDL: MFCD00015318
• Codice UNSPSC: 12352300
• ID PubChem: 24860309
• NACRES: NA.22

Proprietà

• Forma fisica: powder
• Livello qualitativo: 100
• Impiego in reazioni chimiche: core: nickel; reaction type: Cross Couplings; reagent type: catalyst
• Punto di fusione: 213 °C (dec.) (lit.)
• Stringa SMILE: Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4
• InChI: 1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2; ZBQUMMFUJLOTQC-UHFFFAOYSA-L

Descrizione

Applicazioni

Catalyst for:

• Synthesis of block-copolythiophenes
• Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids
• Solid state metathesis polycondensation
• Polymerization of poly(3-alkoxythiophene)s
• Diastereoselective Nozaki-Hiyama-Kishi coupling reactions of C1-C19 fragment of macrolide antibiotic aplyronine A
• Transfer condensation polymerization of conjugated polymers

[1,3-Bis(diphenylphosphino)propane]dichloronickel(II) can be used as a precursor to synthesize metal-fullerene coordination complexes by reduction method.

Informazioni sulla sicurezza

• Pittogrammi: GHS07,GHS08
• Avvertenze: Danger
• Indicazioni di pericolo: H315 - H317 - H319 - H334 - H335 - H350
• Consigli di prudenza: P202 - P261 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• Classi di pericolo: Carc. 1A - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
• Organi bersaglio: Respiratory system
• Codice della classe di stoccaggio: 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable
• Dispositivi di protezione individuale: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges