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288055

Sigma-Aldrich

Cyclopentadienylmanganese(I) tricarbonyl

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About This Item

Formula condensata:
C5H5Mn(CO)3
Numero CAS:
12079-65-1
Peso molecolare:
204.06
Numero CE:
235-142-4
Numero MDL:
MFCD00001440
Codice UNSPSC:
12352103
ID PubChem:
24857312
NACRES:
NA.23

Stato

powder or crystals

Composizione

Mn, 26.0-27.9% EDTA titration

Impiego in reazioni chimiche

core: manganese
reagent type: catalyst

Punto di fusione

72-76 °C (lit.)

Stringa SMILE

[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1

InChI

1S/C5H5.3CO.Mn/c1-2-4-5-3-1;3*1-2;/h1-5H;;;;
CZPHEHHRMHXAIK-UHFFFAOYSA-N

Categorie correlate

Pittogrammi

Skull and crossbones
GHS06

Avvertenze

Danger

Indicazioni di pericolo

H300

Consigli di prudenza

P264 - P301 + P310

Classi di pericolo

Acute Tox. 2 Oral

Codice della classe di stoccaggio

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificati d'analisi (COA)

Lot/Batch Number
MKCF2541
MKCD8175
MKBZ0743V
MKBZ0742V
MKBX8112V

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Sigma-Aldrich

119318

Benzene-chromium(0) tricarbonyl

I Rémy et al.
Journal of pharmaceutical and biomedical analysis, 9(10-12), 965-967 (1991-01-01)
Biotin labelled with a cymantrene moiety (cyclopentadienyl manganese tricarbonyl complex) is described for the first time. Because this metallo-biotin retains full recognition for the specific glycoprotein avidin (or streptavidin), the labelled streptavidin-biotin system is proposed for use in a solid-phase
Katrin Splith et al.
Bioconjugate chemistry, 21(7), 1288-1296 (2010-07-01)
Over the past years, numerous promising new metalorganic lead structures have been developed exhibiting highly active cytostatic properties. However, the efficiency of such chemotherapeutics in the treatment of tumors is often limited by their low therapeutic index due to their
Ricardo Picciochi et al.
The journal of physical chemistry. A, 112(41), 10429-10434 (2008-09-20)
The standard molar enthalpy of sublimation of monoclinic cyclopentadienyltricarbonylmanganese, Mn(eta (5)-C 5H 5)(CO) 3, at 298.15 K, was determined as Delta sub H m (o)[Mn(eta (5)-C 5H 5)(CO) 3] = 75.97 +/- 0.37 kJ x mol (-1) from Knudsen effusion
J Zayed et al.
American Industrial Hygiene Association journal, 55(1), 53-58 (1994-01-01)
Occupational and environmental exposure to airborne manganese has been measured for two groups of workers in Montreal, taxi drivers and garage mechanics. In Canada methylcyclopentadienyl manganese tricarbonyl (MMT) has replaced lead as an anti-knock agent in gasoline and represents a
R J Clay et al.
Toxicology and applied pharmacology, 98(3), 434-443 (1989-05-01)
The acute pneumotoxic effects of cyclopentadienyl manganese tricarbonyl (CMT) and methylcyclopentadienyl manganese tricarbonyl (MMT) were compared to delineate the role of the methyl side chain in the toxicity of these organomanganese compounds and to further our understanding of the mechanisms
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