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Documenti fondamentali

261262

Sigma-Aldrich

Scandium

powder, 99.9% trace rare earth metals basis

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About This Item

Formula empirica (notazione di Hill):
Sc
Numero CAS:
Peso molecolare:
44.96
Numero CE:
Numero MDL:
Codice UNSPSC:
12141613
ID PubChem:
NACRES:
NA.23

Livello qualitativo

Saggio

99.9% trace rare earth metals basis

Forma fisica

powder

Resistività

50.5 μΩ-cm, 0°C

P. eboll.

2836 °C (lit.)

Punto di fusione

1540 °C (lit.)

Densità

2.99 g/mL at 25 °C (lit.)

Stringa SMILE

[Sc]

InChI

1S/Sc
SIXSYDAISGFNSX-UHFFFAOYSA-N

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Applicazioni

Employed in solid state synthesis of unusual clusters, Sc19Br28Z4, (Z=Mn, Fe, Ru or Os). These clusters are of interest for their structure and magnetic properties.

Accessorio

N° Catalogo
Descrizione
Determinazione del prezzo

Pittogrammi

Flame

Avvertenze

Danger

Indicazioni di pericolo

Consigli di prudenza

Classi di pericolo

Flam. Sol. 1

Codice della classe di stoccaggio

4.1B - Flammable solid hazardous materials

Classe di pericolosità dell'acqua (WGK)

nwg

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Certificati d'analisi (COA)

Lot/Batch Number

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Yttrium chips, 99.9% trace rare earth metals basis

Sigma-Aldrich

262994

Yttrium

Wei Li et al.
Angewandte Chemie (International ed. in English), 51(34), 8644-8647 (2012-07-24)
Asymmetric expansion: A catalytic asymmetric ring-expansion reaction of the title compounds occurs in the presence of a Sc(OTf)(3) catalyst bearing an N,N'-dioxide-based ligand. Highly functionalized 2-quinolone derivatives containing a chiral C4-quaternary stereocenter were obtained in high yields and high levels
Subrata Kundu et al.
Journal of the American Chemical Society, 134(36), 14710-14713 (2012-08-30)
High-valent copper-nitrene intermediates have long been proposed to play a role in copper-catalyzed aziridination and amination reactions. However, such intermediates have eluded detection for decades, preventing the unambiguous assignments of mechanisms. Moreover, the electronic structure of the proposed copper-nitrene intermediates
Hiroshi Inaba et al.
Dalton transactions (Cambridge, England : 2003), 41(37), 11424-11427 (2012-08-15)
We have succeeded in preparing semi-synthesized proteins bound to Sc(3+) ion which can promote an epoxide ring-opening reaction. The Sc(3+) binding site was created on the surface of [(gp5βf)(3)](2) (N. Yokoi et al., Small, 2010, 6, 1873) by introducing a
Nadine V Hanhan et al.
Organic letters, 14(9), 2218-2221 (2012-04-18)
The scandium(III)-catalyzed enantioselective Hosomi-Sakurai allylation of isatins with various substituted allylic silanes is described. A catalyst loading as low as 0.05 mol % is utilized at room temperature to afford the 3-allyl-3-hydroxy-2-oxindoles in excellent yields and enantioselectivity up to 99%
Marek Pruszyński et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 70(6), 974-979 (2012-04-03)
The positron-emitting radionuclide (44)Sc with a half-life of 3.97 h and a β(+) branching of 94.3% is of potential interest for clinical PET. As so far it is available from a (44)Ti/(44)Sc generator in Mainz, where long-lived (44)Ti decays to

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