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Key Documents

Altri documenti

236357

Sigma-Aldrich

3-Hydroxypropionitrile

ReagentPlus®, 99%

Sinonimo/i:

2-Cyanoethanol, Ethylene cyanohydrin, Hydracrylonitrile

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About This Item

Formula condensata:
HOCH2CH2CN
Numero CAS:
109-78-4
Peso molecolare:
71.08
Beilstein:
635773
Numero MDL:
MFCD00002826
Codice UNSPSC:
12352100
ID PubChem:
24854166
NACRES:
NA.22

Densità del vapore

2.5 (vs air)

Livello qualitativo

200

Tensione di vapore

<0.1 mmHg ( 20 °C)

Nome Commerciale

ReagentPlus®

Saggio

99%

Forma fisica

liquid

Temp. autoaccensione

922 °F

Limite di esplosione

12.1 %

Indice di rifrazione

n20/D 1.425 (lit.)

P. eboll.

228 °C (lit.)

Punto di fusione

−46 °C (lit.)

Solubilità

diethyl ether: slightly soluble 2.3 % (w/w) at 15 °C(lit.)
acetone: miscible(lit.)
benzene: insoluble(lit.)
carbon disulfide: insoluble(lit.)
carbon tetrachloride: insoluble(lit.)
ethanol: miscible(lit.)
petroleum ether: insoluble(lit.)
water: miscible(lit.)

Densità

1.04 g/mL at 25 °C (lit.)

Temperatura di conservazione

2-8°C

Stringa SMILE

OCCC#N

InChI

1S/C3H5NO/c4-2-1-3-5/h5H,1,3H2
WSGYTJNNHPZFKR-UHFFFAOYSA-N

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Categorie correlate

Applicazioni

3-Hydroxypropionitrile has been used:
  • as polar solvent to investigate the orientation of the phospholipid at the surface of the polar solvents by neutral impact collision ion scattering spectroscopy
  • in solid state composite electrolyte for dye-sensitized solar cells
  • as a reagent for carboxyl protection in peptide synthesis

Note legali

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Codice della classe di stoccaggio

10 - Combustible liquids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

235.4 °F - closed cup

Punto d’infiammabilità (°C)

113 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Certificati d'analisi (COA)

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Hongxia Wang et al.
The journal of physical chemistry. B, 110(12), 5970-5974 (2006-03-24)
It was observed that the ionic conductivity of the solid-state electrolyte LiI/3-hydroxypropionitrile (HPN) = 1:4 (molar ratio) decreased dramatically with increasing iodine (I(2)) concentration, which differs from the conduction behavior of the Grotthuss transport mechanism observed in liquid or gel
3-hydroxypropionitrile: A new reagent for carboxyl protection in peptide synthesis.
Misra PK, et al.
Tetrahedron Letters, 30(27), 3569-3572 (1989)
Hartwig Pohl et al.
Langmuir : the ACS journal of surfaces and colloids, 26(4), 2473-2476 (2009-11-20)
Phospholipids are a main component of cell membranes. Therefore, the experimental investigation of the self-organization of phospholipids is of great interest. Here we present results concerning the orientation of the phospholipid 1-palmitoyl-2-oleoyl-sn-glycero-3-phosphocholine (POPC) at the surface of the polar solvents
M Duverger-Van Bogaert et al.
Toxicology letters, 7(4-5), 311-319 (1981-02-01)
The mutagenicity of acrylonitrile (ACN) was tested with Salmonella typhimurium TA1530 after a preincubation period of the chemical with a rat liver post-mitochondrial fraction in liquid medium. Several pretreatments were applied to the animals before the preparation of the liver
M Lambotte-Vandepaer et al.
Toxicology letters, 7(4-5), 321-327 (1981-02-01)
Urines collected from rats injected with acrylonitrile (ACN) were mutagenic towards Salmonella typhimurium TA1530; this activity was reduced when the animals were pretreated by pyrazole (inhibitor of alcohol dehydrogenase) and suppressed after pretreatment either by CoCl2 and SKF 525-A (inhibitors
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