189901

Methylmagnesium chloride solution

3.0 M in THF

• Sinonimo/i: Chloromethylmagnesium, Methyl magnesium chloride, Methylmagnesiumchloride
• Formula condensata: CH₃MgCl
• Numero CAS: 676-58-4
• Peso molecolare: 74.79
• Beilstein: 3587199
• Numero MDL: MFCD00000468
• Codice UNSPSC: 12352103
• ID PubChem: 24851404
• NACRES: NA.22

Proprietà

• Temp. autoaccensione: 609 °F
• Livello qualitativo: 200
• Impiego in reazioni chimiche: reaction type: Grignard Reaction
• Concentrazione: 3.0 M in THF
• Densità: 1.013 g/mL at 25 °C
• Stringa SMILE: C[Mg]Cl
• InChI: 1S/CH3.ClH.Mg/h1H3;1H;/q;;+1/p-1; RQNMYNYHBQQZSP-UHFFFAOYSA-M

Descrizione

Applicazioni

Methylmagnesium chloride solution (3 M in THF) undergoes 1,3-addition with dialdose derived nitrones to form N-benzylhydroxylamines. The reductive cleavage of the N-O bond of these N-benzylhydroxylamines results in N-benzylaminosugars, which are key moieties of bioactive compounds. It can also react with Garner type aldehydes to form the corresponding secondary alcohols.

Confezionamento

The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

View returnable container options.

Note legali

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Informazioni sulla sicurezza

• Pittogrammi: GHS02,GHS08,GHS05,GHS07
• Avvertenze: Danger
• Indicazioni di pericolo: H225,H260,H314,H335,H336,H351
• Consigli di prudenza: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Classi di pericolo: Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• Organi bersaglio: Central nervous system, Respiratory system
• Rischi supp: EUH014,EUH019
• Codice della classe di stoccaggio: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• Classe di pericolosità dell'acqua (WGK): WGK 1
• Punto d’infiammabilità (°F): 1.0 °F - closed cup
• Punto d’infiammabilità (°C): -17.2 °C - closed cup
• Dispositivi di protezione individuale: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter