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Documenti fondamentali

185361

Sigma-Aldrich

Terephthalic acid

greener alternative

98%

Sinonimo/i:

Benzene-1,4-dicarboxylic acid

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About This Item

Formula condensata:
C6H4-1,4-(CO2H)2
Numero CAS:
Peso molecolare:
166.13
Beilstein:
1909333
Numero CE:
Numero MDL:
Codice UNSPSC:
12162002
eCl@ss:
39024105
ID PubChem:
NACRES:
NA.23

Tensione di vapore

<0.01 mmHg ( 20 °C)

Livello qualitativo

Saggio

98%

Forma fisica

powder

Temp. autoaccensione

925 °F

Caratteristiche più verdi

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Punto di fusione

>300 °C (lit.)

Solubilità

water: ~0.017 g/L at 25 °C

Densità

1.58 g/cm3 at 25 °C

Categoria alternativa più verde

Stringa SMILE

OC(=O)c1ccc(cc1)C(O)=O

InChI

1S/C8H6O4/c9-7(10)5-1-2-6(4-3-5)8(11)12/h1-4H,(H,9,10)(H,11,12)
KKEYFWRCBNTPAC-UHFFFAOYSA-N

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Descrizione generale

Terephthalic acid belongs to the class of monomers known as aromatic dicarboxylic acids. It is primarily used as a key monomer in the production of a high-performance polymer known as polyethylene terephthalate (PET). It is also used to prepare other polymers such as polybutylene terephthalate (PBT), polymer blends, and alloys. Terephthalic acid-based polymers are widely used in various industries including, packaging, textile fibers, polyester resins, polyurethane coatings, polyurethane foams, protective coatings, electrical components, and automotive applications due to their excellent properties such as high thermal stability, chemical resistance, lightweight, transparency, high strength, and durability. In the medical industry, terephthalic acid-based polymers may be used in the production of medical devices and equipment such as surgical sutures, tissue engineering scaffolds, and vascular grafts due to their biocompatibility, chemical resistance, and ease of processing.

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Applicazioni

Terephthalic acid can be used:
  • As a monomer in the synthesis of poly(butylene terephthalate) (PBT), a type of polyester, that is used in various fields including Automotive components, textile Industry, packaging materials, electrical and electronic components.
  • As an organic ligand in the synthesis of the cobalt(II) metal–organic framework (MOFs), which finds applications in electrochemical energy storage, catalysis, optoelectronics, and water treatment.
  • Terephthalic acid (TPA) can be synthesized from bio-based materials for a variety of applications, which include the production of polyester fiber, non-fiber field, PET bottles, synthetic perfumes and medicines.
  • Terephthalic acid is used as a linker molecule in the preparation of metal-organic frameworks (MOFs).

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves


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Photocatalytic degradation of terephthalic acid using titania and zinc oxide photocatalysts: Comparative study
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Synthesis of ethylene glycol and terephthalic acid from biomass for producing PET
Pang J, et al.
Green Chemistry, 18(2), 342-359 (2016)
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Shane T Kenny et al.
Applied microbiology and biotechnology, 95(3), 623-633 (2012-05-15)
Sodium terephthalate (TA) produced from a PET pyrolysis product and waste glycerol (WG) from biodiesel manufacture were supplied to Pseudomonas putida GO16 in a fed-batch bioreactor. Six feeding strategies were employed by altering the sequence of TA and WG feeding.

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