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159042

Sigma-Aldrich

Luperox® P, tert-Butyl peroxybenzoate

98%

Sinonimo/i:

tert-Butyl peroxybenzoate, tert-Butyl perbenzoate

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About This Item

Formula condensata:
C6H5COOOC(CH3)3
Numero CAS:
614-45-9
Peso molecolare:
194.23
Beilstein:
1342734
Numero CE:
210-382-2
Numero MDL:
MFCD00008802
Codice UNSPSC:
12352100
ID PubChem:
24849787
NACRES:
NA.22

Densità del vapore

6.7 (vs air)

Livello qualitativo

200

Tensione di vapore

3.36 mmHg ( 50 °C)

Saggio

98%

Stato

liquid

Indice di rifrazione

n20/D 1.499 (lit.)

P. ebollizione

75-76 °C/0.2 mmHg (lit.)

Solubilità

water: soluble 1.18 g/L

Densità

1.021 g/mL at 25 °C (lit.)

Gruppo funzionale

peroxide
phenyl

Stringa SMILE

CC(C)(C)OOC(=O)c1ccccc1

InChI

1S/C11H14O3/c1-11(2,3)14-13-10(12)9-7-5-4-6-8-9/h4-8H,1-3H3
GJBRNHKUVLOCEB-UHFFFAOYSA-N

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Descrizione generale

tert-butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane has been reported.

Applicazioni

Luperox was employed as polymerization and cross-linking catalyst. It was also was employed as initiator during:
  • grafting of 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO)-4-oxyacetamido-(3 propyltriethoxysilane) to poly(ethylene co-octene)
  • preparation of conformal poly(cyclohexyl methacrylate) thin films via initiated chemical vapor deposition

Note legali

Product of Arkema Inc.
Luperox is a registered trademark of Arkema Inc.

Avvertenze

Danger

Indicazioni di pericolo

H242,H315,H317,H332,H410

Classi di pericolo

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 3 - Org. Perox. C - Skin Irrit. 2 - Skin Sens. 1

Codice della classe di stoccaggio

4.1A - Other explosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

200.1 °F - closed cup

Punto d’infiammabilità (°C)

93.4 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
MKCQ9513
MKCQ9511
MKCQ9512
MKCN8011
MKCN1787

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Jingjing Xu et al.
ACS applied materials & interfaces, 3(7), 2410-2416 (2011-06-08)
Conformal poly(cyclohexyl methacrylate) (pCHMA) thin films were synthesized via initiated chemical vapor deposition (iCVD), with tert-butyl peroxybenzoate (TBPOB) as the initiator, representing the first time that TBPOB has been used as an initiator for iCVD synthesis. Using TBPOB instead of
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Journal of Polymer Science Part A: Polymer Chemistry, 46(13), 4542-4555 (2008)
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Chemical communications (Cambridge, England), 50(49), 6439-6442 (2014-04-05)
An efficient method for the construction of 6-alkyl phenanthridines by tert-butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane was established. Two new C-C bonds were formed in this reaction via a sequential C(sp(3))-H/C(sp(2))-H bond functionalization under metal-free conditions.
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New tung oil (TO)-based, unsaturated, co-ester (Co-UE) macromonomers bearing steric hindrance were synthesized by modifying a TO-based maleate (TOPERMA) monomer with an anhydride structure with hydroxyethyl methacrylate (HEMA) and methallyl alcohol (MAA), respectively. The obtained Co-UE monomers (TOPERMA-HEMA and TOPERMA-MAA)
Margaret Hanausek et al.
Carcinogenesis, 25(3), 431-437 (2003-11-25)
Screening of newly synthesized organic peroxides for tumor initiating/promoting activity would be greatly facilitated if predictive methodologies could be developed using topical exposures shorter than those required for definitive tumor assessment in mouse skin models. Nine organic peroxides [benzoyl peroxide
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