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C4991

Sigma-Aldrich

头孢甘氨酸

≥97% (HPLC), solid

别名:

NSC 318735

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About This Item

经验公式（希尔记法）:
C45H53NO14
CAS号:
71610-00-9
分子量:
831.90
MDL號碼:
MFCD01075131
分類程式碼代碼:
12352200
PubChem物質ID:
24724441
NACRES:
NA.77

化驗

≥97% (HPLC)

形狀

solid

溶解度

DMSO: soluble 14 mg/mL

抗生素活性譜

neoplastics

作用方式

DNA synthesis | interferes

儲存溫度

room temp

SMILES 字串

C\C=C(/C)C(=O)N[C@H]([C@@H](O)C(=O)O[C@H]1C[C@@]2(O)[C@@H](OC(=O)c3ccccc3)C4[C@@](C)([C@@H](O)C[C@H]5OC[C@@]45OC(C)=O)C(=O)[C@H](OC(C)=O)C(=C1C)C2(C)C)c6ccccc6

InChI

1S/C45H53NO14/c1-9-23(2)39(52)46-33(27-16-12-10-13-17-27)34(50)41(54)58-29-21-45(55)38(59-40(53)28-18-14-11-15-19-28)36-43(8,30(49)20-31-44(36,22-56-31)60-26(5)48)37(51)35(57-25(4)47)32(24(29)3)42(45,6)7/h9-19,29-31,33-36,38,49-50,55H,20-22H2,1-8H3,(H,46,52)/b23-9+/t29-,30-,31+,33-,34+,35+,36?,38-,43+,44-,45+/m0/s1

InChI 密鑰

DBXFAPJCZABTDR-UJLUYDJNSA-N

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一般說明

化学结构:β-内酰胺

應用

头孢甘氨酸已被用于鉴定液体培养物中的真菌紫杉醇（抗癌药）。

生化／生理作用

头孢甘氨酸是从红豆杉中分离得到的，可用作抗真菌剂。
三尖杉宁碱是一种具有抗肿瘤、抗增殖特性的紫杉醇衍生物。

象形圖

CorrosionExclamation mark
GHS05,GHS07

訊號詞

Danger

危險聲明

H315,H318,H335

危險分類

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)

分析证书(COA)

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Sigma-Aldrich

C4895

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紫杉醇 from semisynthetic, ≥98%

Sigma-Aldrich

T7191

紫杉醇

Interactions between co-habitating fungi elicit synthesis of Taxol from an endophytic fungus in host Taxus plants
Soliman Sameh SM and Raizada MN
Frontiers in Microbiology, 4, 3-3 (2013)
Rui Sun et al.
Journal of separation science, 32(9), 1284-1293 (2009-04-11)
An environment-friendly method was established for the preparative separation and enrichment of four taxoids, namely 10-deacetylbaccatin III (10-DAB III), 7-xylosyl-10-deacetyltaxol (7-xyl-10-DAT), cephalomannine and paclitaxel from Taxus chinensis needles extracts. Characteristics of seven widely used macroporous resins for four taxoids were
K Glowniak et al.
Phytomedicine : international journal of phytotherapy and phytopharmacology, 6(2), 135-140 (1999-06-22)
The concentrations of four common taxoids: baccatin III, paclitaxel, cephalomannine and 10-deacetylbaccatin III (10-DAB III) were measured in fresh needles and stems of Taxus baccata L. during the late autumn-spring period (November'96-April'97) which has not been investigated to date in
Synthesis, isolation, stereostructure and cytotoxicity of paclitaxel analogs from cephalomannine
Gao, Feng and Wang, Dan and Huang, Xing
Fitoterapia, 90, 79-84 (2013)
K C Chan et al.
Journal of chromatography. B, Biomedical applications, 657(2), 301-306 (1994-07-15)
High-performance liquid chromatography (HPLC) and micellar electrokinetic chromatography (MEKC) were applied for the separation of taxol, cephalomannine, and baccatin III in crude extracts from the needle and bark of Taxus species. The chromatogram of the bark extract was cleaner than
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