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等級
ACS reagent
品質等級
化驗
≥99.8%
99.8-100.3% dry basis (ACS specification)
形狀
crystalline powder
反應適用性
reagent type: oxidant
雜質
≤0.02% other halogens (as Cl)
pH值
3.5-5.5 (25 °C, 107 g/L)
mp
300 °C (dec.) (lit.)
正離子痕跡
Mn: ≤3 ppm
儲存溫度
room temp
SMILES 字串
[Na+].[O-]I(=O)(=O)=O
InChI
1S/HIO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
InChI 密鑰
JQWHASGSAFIOCM-UHFFFAOYSA-M
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一般說明
高碘酸钠是一种无机盐,通常用作各种有机底物的氧化剂和其他一些氧化反应的助氧化剂。高碘酸钠的氧化发生在水介质中,但有机助溶剂用于不溶于水的有机基质。
應用
高碘酸钠可用作氧化剂:
- 将硫化物选择性氧化为亚砜。
- 氧化裂解各种 1,2-二醇以生成醛类或酮类。
- 将二芳基、二烷基和芳基烷基硒化物氧化为各自的硒氧化物。
- 选择性烯烃环氧化和烷烃羟基化反应。
- 选择性氧化活性纤维素,以通过裂解葡萄糖单元中 C2 – C3 之间的键得到双醛纤维素(DAC)。
- 它还可用作芳烃和卤素化合物的碘化剂。
訊號詞
Danger
危險分類
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 1 - Skin Corr. 1C - STOT RE 1
標靶器官
Thyroid
儲存類別代碼
5.1A - Strongly oxidizing hazardous materials
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
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