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Merck

60080

Sigma-Aldrich

硼氢化钾

purum, ≥97.0% (RT)

别名:

硼氢化钾

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About This Item

线性分子式:
KBH4
CAS号:
分子量:
53.94
EC號碼:
MDL號碼:
分類程式碼代碼:
12352000
PubChem物質ID:
NACRES:
NA.22

等級

purum

品質等級

化驗

≥97.0% (RT)

反應適用性

reagent type: reductant

mp

500 °C (dec.) (lit.)

密度

1.18 g/mL at 25 °C (lit.)

SMILES 字串

[K+].[H][B-]([H])([H])[H]

InChI

1S/BH4.K/h1H4;/q-1;+1

InChI 密鑰

ICRGAIPBTSPUEX-UHFFFAOYSA-N

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應用

Potassium borohydride can be used:
  • As a reducing agent and boron source in organic synthesis.
  • As a reducing agent in the preparation of copper nanoparticles.
  • To reduce toxic 2-nitroaniline to less toxic o-phenylenediamine using different catalytic systems.

Reactant commonly used as a reducing agent and as a boron source

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react 1

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類(WGK)

nwg

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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分析证书(COA)

Lot/Batch Number

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Reduction of nitroarenes to azoxybenzenes by potassium borohydride in water
Liu Y, et al.
Molecules (Basel), 16(5), 3563-3568 (2011)
Low-temperature solid state synthesis and in situ phase transformation to prepare nearly pure cBN
Lian G, et al.
Dalton Transactions, 40(26), 6961-6967 (2011)
S. Yan and S. Zhang,
International Journal of Hydrogen Energy, 36, 13392-13397 (2011)
A. Yin, et al.,
Applied Catalysis, 400, 39-47 (2011)
Gang Lian et al.
Dalton transactions (Cambridge, England : 2003), 40(26), 6961-6967 (2011-06-07)
Cubic boron nitride (cBN) is synthesized by a low-temperature solid state synthesis and in situ phase transformation route with NH(4)BF(4), B, NaBH(4) and KBH(4) as the boron sources and NaN(3) as the nitrogen source. Furthermore, two new strategies are developed

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