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Merck

35620

Supelco

2,6-二氯醌-4-氯亚胺

for spectrophotometric det. of vitamin B6, ≥99.0%

别名:

2,6-二氯苯醌氯亚胺, Gibb 试剂

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About This Item

经验公式(希尔记法):
C6H2Cl3NO
CAS号:
分子量:
210.45
Beilstein:
2364249
EC號碼:
MDL號碼:
分類程式碼代碼:
41116105
PubChem物質ID:
NACRES:
NA.21

品質等級

化驗

≥99.0% (AT)
≥99.0%

品質

for spectrophotometric det. of vitamin B6

技術

UV/Vis spectroscopy: suitable

mp

65-67 °C (lit.)
65-68 °C

應用

food and beverages
vitamins, nutraceuticals, and natural products

儲存溫度

2-8°C

SMILES 字串

Cl\N=C1\C=C(Cl)C(=O)C(Cl)=C1

InChI

1S/C6H2Cl3NO/c7-4-1-3(10-9)2-5(8)6(4)11/h1-2H

InChI 密鑰

YHUMTHWQGWPJOQ-UHFFFAOYSA-N

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一般說明

2,6-Dichloroquinone-4-chloroimide generally find application in being used as spot test and chromatographic spray reagents, mainly for phenols, though it can be used in detection of other types of compounds such as antioxidants, few primary and secondary amines, on silica gel chromatographic plates. Its decomposition rate is directly proportional to pressure.

應用

Gibb′s reagent was used in paper chromatography, in an experiment conducted to semi-quantitatively estimate tyramine and octopamine.

象形圖

FlameExclamation mark

訊號詞

Danger

危險聲明

危險分類

Eye Irrit. 2 - Self-react. C - Skin Irrit. 2

儲存類別代碼

4.1A - Other explosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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分析证书(COA)

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Colour reaction of phenols with the gibbs reagent. The reaction mechanism and decomposition and stabilisation of the reagent.
Svobodova D
Microchimica Acta, 67 (3-4), 251-264 (1977)
P Miller et al.
Clinical chemistry, 36(4), 668-669 (1990-04-01)
In this nonenzymatic colorimetric method, dichlorobenzoquinone chloroimine is used as a color reagent to measure uric acid in urine. This method is less subject to the interferences that make enzymatic methods unreliable and is inexpensive, simple, and fast.
Colorimetric determination of prenalterol hydrochloride in dosage forms.
F A Aly et al.
Journal of pharmaceutical and biomedical analysis, 12(7), 955-958 (1994-07-01)
G G Mohamed et al.
Journal of pharmaceutical and biomedical analysis, 28(6), 1127-1133 (2002-06-07)
A simple, rapid and sensitive spectrophotometric method for the determination of sulbutamol in pure form and in different pharmaceutical preparations has been developed. The charge transfer (CT) reaction between salbutamol as electron donor and 2,6-dichloroquinone chlorimide (DCQ) and 7,7,8,8-tetracyanoquinodimethane (TCNQ)
Mohammad-Wadud Bhuiya et al.
Analytical biochemistry, 384(1), 151-158 (2008-10-18)
S-adenosyl-L-methionine (AdoMet)-dependent O-methyltransferases (OMTs) catalyze the transmethylation of a variety of phenolics in bacteria, plants, and humans. To rapidly characterize phenolic OMT activities, we adapted Gibbs' reagent, the dye originally used for detecting phenols, to develop a convenient assay method

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