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Merck

M11103

Sigma-Aldrich

4-甲氧基苄胺

98%

别名:

1-氨甲基-4-甲氧基苯, 4-甲氧基苯甲胺, 对甲氧基苄胺, 山莨菪碱, (4-甲氧基苯基)甲胺, (对甲氧基苯基)甲胺

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About This Item

线性分子式:
CH3OC6H4CH2NH2
CAS号:
分子量:
137.18
Beilstein:
508206
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

形狀

liquid

折射率

n20/D 1.546 (lit.)

bp

236-237 °C (lit.)

密度

1.05 g/mL at 25 °C (lit.)

SMILES 字串

COc1ccc(CN)cc1

InChI

1S/C8H11NO/c1-10-8-4-2-7(6-9)3-5-8/h2-5H,6,9H2,1H3

InChI 密鑰

IDPURXSQCKYKIJ-UHFFFAOYSA-N

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應用

4-甲氧基苄胺属于一级胺,可用于:
  • 官能化芳基溴的胺化反应。
  • 合成体内应用的官能化有机聚磷腈。
  • 合成具有抗增殖活性的肌球蛋白、8-氮杂嘌呤类似物。
  • 研究2-硝基-和2,4-二硝基苯磺酰胺等氨基保护基团的脱保护步骤。

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Anna Berlicka et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 9(10), 1359-1366 (2010-09-08)
A variety of primary and secondary benzylic amines were oxidized efficiently to N-benzylidenebenzylamines and imines, respectively, using 2,7,12,17-tetrapropylporphycene (H(2)TPrPc) photocatalyst and blue light emitting diodes (LEDs). The photooxidation of 4-methoxybenzylamine in the presence of H(2)TPrPc and its tin(IV) complex Sn(TPrPc)Cl(2)
Synthesis and biological activity of 8-azapurine and pyrazolo [4, 3-d] pyrimidine analogues of myoseverin.
Krystof V, et al.
European Journal of Medicinal Chemistry, 41(12), 1405-1411 (2006)
Synthesis and characterization of novel polyorganophosphazenes substituted with 4-methoxybenzylamine and 4-methoxyphenethylamine for in vitro release of indomethacin and 5-fluorouracil.
Gudasi KB, et al.
Reactive and Functional Polymers, 66(10), 1149-1157 (2006)
Mild and efficient copper-catalyzed amination of aryl bromides with primary alkylamines.
Kwong FY and Buchwald SL
Organic Letters, 5(6), 793-796 (2003)
T Jonsson et al.
Biochemistry, 33(49), 14871-14878 (1994-12-13)
Competitive kH/kT and kD/kT kinetic isotope effects on p-methoxybenzylamine oxidation by the 8 alpha-S-cysteinyl flavin adenine dinucleotide (FAD)-dependent enzyme monoamine oxidase B (MAO-B) have been measured as a function of temperature. At pH 7.5, exponents relating observed kH/kT and kD/kT

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