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Merck

C109207

Sigma-Aldrich

1,5-环辛二烯

contains 50-150 ppm 4-tert-Butylcatechol, 99%

别名:

1,5-COD, cis-1,5-Cyclooctadiene, COD

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About This Item

经验公式(希尔记法):
C8H12
CAS号:
分子量:
108.18
Beilstein:
2036542
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽壓力

25.8 mmHg ( 37.7 °C)
6.8 mmHg ( 25 °C)

化驗

99%

形狀

liquid

自燃溫度

431 °F

包含

50-150 ppm 4-tert-Butylcatechol as stabilizer
50-150 ppm 4-tert-Butylcatechol

折射率

n20/D 1.493 (lit.)

bp

149-150 °C (lit.)

mp

−69 °C (lit.)

密度

0.882 g/mL at 25 °C (lit.)

SMILES 字串

C1CC=CCCC=C1

InChI

1S/C8H12/c1-2-4-6-8-7-5-3-1/h1-2,7-8H,3-6H2/b2-1-,8-7-

InChI 密鑰

VYXHVRARDIDEHS-QGTKBVGQSA-N

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應用

  • Bis(Aluminyl)Magnesium: A Source of Nucleophilic or Radical Aluminium-Centred Reactivity.: Investigates 1,5-Cyclooctadiene′s ability to stabilize reactive intermediates in metal complexes, which is crucial for developing new pharmaceutical agents and enhancing ligand efficiency in transition metal catalysis (Griffin et al., 2024).

訊號詞

Danger

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 3

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

100.4 °F - closed cup

閃點(°C)

38 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Eleonora Cavallari et al.
The journal of physical chemistry. B, 119(31), 10035-10041 (2015-07-15)
Hyperpolarization of (13)C carboxylate signals of metabolically relevant molecules, such as acetate and pyruvate, was recently obtained by means of ParaHydrogen Induced Polarization by Side Arm Hydrogenation (PHIP-SAH). This method relies on functionalization of the carboxylic acid with an unsaturated
Adrian Tlahuext-Aca et al.
Dalton transactions (Cambridge, England : 2003), 43(42), 15997-16005 (2014-09-19)
Ni(0)-catalyzed dehydrogenation of benzylic-type imines was performed to yield asymmetrical tetra-substituted imidazoles and 2-imidazolines. This was achieved with a single operational step while maintaining good selectivity and atom economy. The catalytic system shows low to moderate tolerance for fluoro-, trifluoromethyl-

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