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Merck

A8524

Sigma-Aldrich

苯胺 盐酸盐

≥99%

别名:

Anilinium chloride, Benzenamine hydrochloride, Phenylamine hydrochloride, Phenylammonium chloride

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About This Item

线性分子式:
C6H5NH2 · HCl
CAS号:
分子量:
129.59
Beilstein:
3593823
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

4.46 (vs air)

品質等級

化驗

≥99%

形狀

crystals

mp

196-198 °C (lit.)

SMILES 字串

Cl.Nc1ccccc1

InChI

1S/C6H7N.ClH/c7-6-4-2-1-3-5-6;/h1-5H,7H2;1H

InChI 密鑰

MMCPOSDMTGQNKG-UHFFFAOYSA-N

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生化/生理作用

苯胺的急性毒性与其体内活化生成4-羟基苯胺并与血红蛋白形成加合物有关。在红细胞中,这与铁的释放和高铁血红蛋白的积累以及溶血性贫血和脾脏炎症的发展有关。长期给药经常在脾脏中观察到肿瘤形成。

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Muta. 2 - Skin Sens. 1 - STOT RE 1

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

381.2 °F - closed cup

閃點(°C)

194 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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分析证书(COA)

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Hannelore Jasch et al.
The Journal of organic chemistry, 77(23), 10699-10706 (2012-11-08)
Substituted 2-aminobiphenyls have been prepared from arylhydrazines and anilines via radical arylation reactions under simple oxidative conditions. The strong directing effect of the free and unprotonated amino functionality leads to high regioselectivities, and anilines have been shown to be significantly
Conghui Tang et al.
Journal of the American Chemical Society, 134(46), 18924-18927 (2012-11-08)
A novel and efficient copper-catalyzed azidation reaction of anilines via C-H activation has been developed. This method, in which the primary amine acts as a directing group by coordinating to the metal center, provides ortho azidation products regioselectively under mild
Brandon Djukic et al.
The Journal of organic chemistry, 78(18), 9340-9344 (2013-08-27)
The synthesis and electrochemical oxidative coupling of a highly electron-deficient analogue of aniline results in the formation of soluble electron-deficient oligomers. Oligomers undergo related oxidation and reduction processes that are separated by a wide potential range. The mechanism behind this
Cheng Xue et al.
Biosensors & bioelectronics, 49, 199-203 (2013-06-12)
In this work, a highly sensitive and selective biomimetic electrochemical sensor for the amperometric detection of trace dopamine (DA) in human serums was achieved by gold nanoparticles (AuNPs) doped molecularly imprinted polymers (MIPs). Functionalized AuNPs (F-AuNPs), a novel functional monomer
Roman Spesyvtsev et al.
Faraday discussions, 157, 165-179 (2012-12-13)
Femtosecond time-resolved photoelectron imaging is employed to investigate ultrafast electronic relaxation in aniline, a prototypical aromatic amine. The molecule is excited at wavelengths between 269 and 238 nm. We observe that the S2(pi3s/pi sigma*) state is populated directly during the

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