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一般說明
Synonym: 2,2′-((2Z,2′Z)-((12,13-bis(2-ethylhexyl)-3,9-diundecyl-12,13-dihydro-[1,2,5]thiadiazolo[3,4-e]thieno[2",3":4′,5′]-thieno[2′,3′:4,5]pyrrolo[3,2-g]thieno[2′,3′:4,5]thieno[3,2-b]indole-2,10-diyl)bis(methanylylidene))bis(5,6-dichloro-3-oxo-2,3-dihydro-1H-indene-2,1-diylidene))dimalononitrile
應用
BTP-4Cl is a high performance, low bandgap, non-fullerene accpetor (NFA). It is the chlorinated derivative of the fused benzothiadiazole-based NFA, Y6. It offer high power conversion efficiency (PCE) when pairing with p-type polymer PM6. A 9 mm2 single junction device of this blend provided a PCE of 16.5% at thickness of ~ 100nm, and provided a PCE of >13% at a thickness of ~300 nm (for the active layer). An impressive PCE of >15% was reached for this blend with a 1 cm2 active layer. In general, Y7 showed improved performances over Y6, mainly due to its highest photoluminescence, lower non-radiative energy loss, and a higher Voc of 0.867 V vs 0.834 V for Y6.
Y7 is a highly conjugated organic semiconductor, electron deficient due to its structure and hence suitable for use as a n-type non-fullerene electron acceptor(NFA) in OPV devices. It has an absorption range that extends to the near infrared (NIR) and has demonstrated a power conversion efficiency (PCE) up to15.7% with PBDB-T-2F (PM6) as the polymer donor.
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
Yong Cui et al.
Nature communications, 10(1), 2515-2515 (2019-06-09)
Broadening the optical absorption of organic photovoltaic (OPV) materials by enhancing the intramolecular push-pull effect is a general and effective method to improve the power conversion efficiencies of OPV cells. However, in terms of the electron acceptors, the most common
相关内容
Organic electronics utilizes organic conductors and semiconductors for applications in organic photovoltaics, organic light-emitting diodes, and organic field-effect transistors.
Organic electronics utilizes organic conductors and semiconductors for applications in organic photovoltaics, organic light-emitting diodes, and organic field-effect transistors.
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