88723

(R)-1-[(S_P)-2-(二环己基膦)二茂铁基乙基]二苯基膦

≥97%

• 别名: (1R)-1-(二环己基膦)-2-[(1R)-1-(二苯基膦)乙基]二茂铁（符合 CAS 标准）, Josiphos SL-J004-1
• 经验公式（希尔记法）: C₃₆H₄₄FeP₂
• CAS号: 158923-09-2
• 分子量: 594.53
• MDL號碼: MFCD00800280
• 分類程式碼代碼: 12352005
• PubChem物質ID: 24888991
• NACRES: NA.22

属性

• 品質等級: 100
• 化驗: ≥97%
• 形狀: crystals
• 光學純度: ee: ≥99%
• 官能基: phosphine
• SMILES 字串: [Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(C3CCCCC3)C4CCCCC4)P(c5ccccc5)c6ccccc6
• InChI: 1S/C31H39P2.C5H5.Fe/c1-25(32(26-15-6-2-7-16-26)27-17-8-3-9-18-27)30-23-14-24-31(30)33(28-19-10-4-11-20-28)29-21-12-5-13-22-29;1-2-4-5-3-1;/h2-3,6-9,14-18,23-25,28-29H,4-5,10-13,19-22H2,1H3;1-5H;/t25-;;/m1../s1
• InChI 密鑰: AWOOIDCKLIQAJV-KHZPMNTOSA-N

说明

一般說明

与 Solvias AG 合作销售

應用

(R)-1-[(S_P)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine can be used as a ligand:

• To prepare iridium metal complex (Ir^IJOSIPHOS), which is used as a catalyst in the asymmetric hydrogenation of 2-phenylquinoxaline.
• In the preparation of natural products by asymmetric conjugate addition of Grignard reagents to α-substituted cyclic alkenones.

包裝

Bottomless glass bottle. Contents are inside inserted fused cone.

安全信息

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: Eyeshields, Gloves, type N95 (US)