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Merck

86870

Sigma-Aldrich

四丁基氯化铵

greener alternative

≥97.0% (NT)

别名:

N,N,N-tributyl-butanaminium chloride

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About This Item

线性分子式:
[CH3(CH2)3]4NCl
CAS号:
分子量:
277.92
Beilstein:
3571227
EC號碼:
MDL號碼:
分類程式碼代碼:
12352107
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥97.0% (NT)

形狀

crystals

環保替代產品特色

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

雜質

≤1% water

溶解度

H2O: 20 mg/mL, clear, colorless

環保替代類別

SMILES 字串

[Cl-].CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.ClH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1

InChI 密鑰

NHGXDBSUJJNIRV-UHFFFAOYSA-M

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相关类别

一般說明

四丁基氯化铵是一种季铵盐,通常用作相转移催化剂以及有机合成中的氯离子源。

我们致力于为您带来更环保的替代产品,以符合绿色化学 12 项原则的一项或多项原则要求该产品为增强型,提高了能源效率。点击此处,查看更多详情。

應用

四丁基氯化铵 (TBACl) 可用作相转移催化剂用于合成:
  • 2-氨基-4H-色烯衍生物,通过醛、丙二腈 和 α或 β-萘酚缩合反应制备。
  • 甲酯,通过羧酸和碳酸二甲酯在K2CO3参与下的酯化反应生成。
它还可被用作引发剂,用于通过 o-异氰基二苯基胺的级联自由基加成/环化合成 11-三氟甲基二苯并二氮杂卓。

TBACl 还可被用于与五氧化二磷一起用于更绿色的脱氧氯化反应。

Pr制备卤代杂芳基化合物。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

235.4 °F - closed cup

閃點(°C)

113 °C - closed cup

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Nancy AlHaddad et al.
Organic & biomolecular chemistry, 17(31), 7330-7336 (2019-07-18)
The present study describes the synthesis of the first phenoxycalix[4]pyrrole-epichlorohydrin based polymer. The advantage of the latter resides in its fast-single step synthesis protocol, low cost, water insolubility and its unexpected anion extraction capacity. The study of this polymer by
I P E Macário et al.
Scientific reports, 9(1), 3932-3932 (2019-03-10)
The tailor-made character of deep eutectic solvents (DES) turns them very attractive to be used in several applications, including in health-related areas such as pharmaceutical, nutraceutical, and cosmetic industries. However, although DES has been touted as "green" solvents, several works
Chao Zhong et al.
Carbohydrate polymers, 94(1), 38-45 (2013-04-03)
In this article, a novel and high efficient solvent, tetra-n-Butylammonium Hydroxide (TBAH), was used for dissolution and isolation of straw cellulose from wheat straw. The composition analysis with gas chromatography (GC) and the spectroscopic characterization analysis conducted by X-Ray diffraction
R Bryan Sears et al.
Journal of inorganic biochemistry, 121, 77-87 (2013-01-29)
The complex cis-[Ru(phpy)(phen)(CH3CN)2](+) (phpy=2-phenylpyridine, phen=1,10-phenanthroline) was investigated as a potential photodynamic therapy (PDT) agent. This complex presents desirable photochemical characteristics including a low energy absorption tail extending into the PDT window (600-850nm) and photoinduced exchange of the CH3CN ligands, generating
Oliver Bixner et al.
The Journal of chemical physics, 136(20), 204503-204503 (2012-06-07)
The interaction of exciton and charge transfer (CT) states plays a central role in photo-induced CT processes in chemistry, biology, and physics. In this work, we use a combination of two-dimensional electronic spectroscopy (2D-ES), pump-probe measurements, and quantum chemistry to

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