809330

硝基化合物的还原反应用Fe/ppm Pd

• MDL號碼: MFCD00011005
• 分類程式碼代碼: 12161600
• NACRES: NA.22

属性

• 形狀: solid
• 品質等級: 100
• 成份: FeCl₂ (372870), 23.3-27.4 wt. % ; MgCl₂ (M8266), 15.3-18.8 wt. % ; Pd (203939), <0.3 wt. % ; THF (186562), 53.5-61.6 wt. %
• 反應適用性: core: iron; reagent type: catalyst
• 儲存溫度: 2-8°C

说明

應用

When these nanoparticles (NPs) are used along with PEG-containing designer surfactants such as TPGS-750-M, a facile reduction of nitro compounds can be effected in water at room temperature. The transformation is highly chemoselective and tolerates a large variety of functional groups.

注意

Handle under nitrogen and store under argon in refrigerator.

其他說明

Safe and Selective Nitro Group Reductions Catalyzed by Sustainable and Recyclable Fe/ppm Pd Nanoparticles in Water at Room Temperature

Watch Professor Lipshutz talk about Fe/ppm Pd in this webinar:
From milligrams to kilograms: synthetic chemistry following nature′s lead

安全信息

• 象形圖: GHS02,GHS08,GHS05,GHS07
• 訊號詞: Danger
• 危險聲明: H225,H290,H302,H318,H335,H351
• 防範說明: P201 - P210 - P233 - P261 - P280 - P305 + P351 + P338 + P310
• 危險分類: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - STOT SE 3
• 標靶器官: Respiratory system
• 安全危害: EUH018,EUH019
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 2
• 閃點（°F）: 1.4 °F
• 閃點（°C）: -17 °C