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758388

Sigma-Aldrich

Pyrazino[2,3-f][1,10]phenanthroline

99% (HPLC)

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About This Item

经验公式（希尔记法）:
C14H8N4
CAS号:
217-90-3
分子量:
232.24
MDL號碼:
MFCD18447748
分類程式碼代碼:
12352103
PubChem物質ID:
329766739
NACRES:
NA.23

化驗

99% (HPLC)

形狀

solid

mp

310-315 °C

SMILES 字串

c1cnc2c(c1)c3nccnc3c4cccnc24

InChI

1S/C14H8N4/c1-3-9-11(15-5-1)12-10(4-2-6-16-12)14-13(9)17-7-8-18-14/h1-8H

InChI 密鑰

IBOSPAWVGHGUAV-UHFFFAOYSA-N

相关类别

一般說明

Pyrazino[2,3-f][1,10]phenanthroline is a ligand which is used in the synthesis of copper(I)- phenanthroline complexes which are used in molecular device technology and in solar-energy conversion. It functions as an electron acceptor and the electron density is delocalized on the quinoxaline ring. The absorption and emission properties and the excited state lifetimes of these phenanthroline based copper complexes can be fine-tuned easily.

應用

  • As an electron accepting ligand in metal complexes which are used in solar cells.
  • Used in the synthesis of ruthenium (II) complexes which are used as DNA probes.

特點和優勢

Imparts improved directionality of electron transfer in excited copper complexes.

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H302

危險分類

Acute Tox. 4 Oral

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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分析证书(COA)

Lot/Batch Number
MKBZ3470V
MKBK1984

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Ge; Hu; Wei;et al.
Journal of Luminescence, 131, 238-243 (2011)
Yujie Sun et al.
Inorganic chemistry, 47(14), 6427-6434 (2008-06-25)
A series of ruthenium(II) complexes possessing ligands with an extended pi system were synthesized and characterized. The complexes are derived from [Ru(bpy)3](2+) (1, bpy = 2,2'-bipyridine) and include [Ru(bpy)2(tpphz)](2+) (2, tpphz = tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]phenazine), [Ru(bpy)2(dppx)](2+) (3, dppx = 7,8-dimethyldipyrido[3,2-a:2',3'-c]phenazine), [Ru(bpy)2(dppm2)](2+) (4
Synthesis, spectroscopic and electrochemical characterization of copper (I) complexes with functionalized pyrazino [2, 3-f]-1, 10-phenanthroline.
Barrientos, L., Araneda, C., Loeb, B., & Crivelli, I. G.
Polyhedron, 27(4), 1287-1295 (2008)

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