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Merck

731277

Sigma-Aldrich

2-氰基-2-丙基-4-氰基苯二硫代碳酸酯

98% (HPLC)

别名:

2-氰基丙基-4-氰基二硫代苯甲酸酯, 4-氰基苯硫代碳酸-1-氰基-1-甲基乙酯

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About This Item

经验公式(希尔记法):
C12H10N2S2
分子量:
246.35
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.23

化驗

98% (HPLC)

形狀

solid

mp

122-127 °C

SMILES 字串

CC(C)(SC(=S)c1ccc(cc1)C#N)C#N

InChI

1S/C12H10N2S2/c1-12(2,8-14)16-11(15)10-5-3-9(7-13)4-6-10/h3-6H,1-2H3

InChI 密鑰

GLQSCQVGVPUIPC-UHFFFAOYSA-N

一般說明

需要帮助选择正确的可逆加成-断裂链转移剂? 请翻阅单体目录里面的RAFT部分兼容性表格.

應用

用于可控自由基聚合的可逆加成 - 断裂链转移剂;特别适合苯乙烯,丙烯酸酯和丙烯酰胺单体聚合。链转移剂(CTA)

法律資訊

销售仅用于研究目的:请访问sigma-aldrich.com/raftlicense 专利: WO98/01478; WO99/311444

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

防範說明

危險分類

Skin Sens. 1

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

商品

A series of polymerization were carried out using RAFT agents and monomers yielding well-defined polymers with narrow molecular weight distributions. The process allows radical-initiated growing polymer chains to degeneratively transfer reactivity from one to another through the use of key functional groups (dithioesters, trithiocarbonates, xanthates and dithiocarbamates). RAFT agents help to minimize out-of-control growth and prevent unwanted termination events from occurring, effectively controlling polymer properties like molecular weight and polydispersity. RAFT agents are commercially available. RAFT does not use any cytotoxic heavy metal components (unlike ATRP).

RAFT (Reversible Addition Fragmentation chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

RAFT (Reversible Addition Fragmentation chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

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实验方案

RAFT (Reversible Addition-Fragmentation chain Transfer) is a form of living radical polymerization involving conventional free radical polymerization of a substituted monomer in the presence of a suitable chain transfer (RAFT) reagent.

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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