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Merck

700703

Sigma-Aldrich

N-叔丁基-N-(2-甲基-1-苯丙基)-O-(1-苯乙基)羟胺

别名:

2,2,5-三甲基-3-(1-苯基乙氧基)-4-苯基-3-氮杂己烷, 烷氧胺 NMP 引发剂

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About This Item

经验公式(希尔记法):
C22H31NO
分子量:
325.49
MDL號碼:
分類程式碼代碼:
12162002
PubChem物質ID:
NACRES:
NA.23

形狀

liquid

品質等級

折射率

n20/D 1.536

密度

0.968 g/mL at 25 °C

儲存溫度

−20°C

SMILES 字串

CC(C)C(N(OC(C)c1ccccc1)C(C)(C)C)c2ccccc2

InChI

1S/C22H31NO/c1-17(2)21(20-15-11-8-12-16-20)23(22(4,5)6)24-18(3)19-13-9-7-10-14-19/h7-18,21H,1-6H3

InChI 密鑰

FPFRTDOMIFBPBZ-UHFFFAOYSA-N

一般說明

想了解由 Karen Wooley 教授提供的采用 NMP 引发剂的合成反应,请访问 技术聚焦。

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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分析证书(COA)

Lot/Batch Number

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Benoit, D., Chaplinski, V., Braslau, R., Hawker, C.J.
Journal of the American Chemical Society, 121, 3904-3904 (1999)

商品

A detailed article on block copolymer synthesis using a nitroxide-mediated radical polymerization (NMP) approach.

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

We presents an article about a micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization. RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

We presents an article about Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands, and the emergence of living radical polymerization mediated by transition metal catalysts in 1995, which was a seminal piece of work in the field of synthetic polymer chemistry.

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实验方案

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

An article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

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